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Tribology Letters

, Volume 49, Issue 2, pp 313–322 | Cite as

Wear Behavior of (TiB2–TiC)–Ni/TiAl/Ti Gradient Materials Prepared by the FAPAS Process

  • Lifang Hu
  • Shaoping Chen
  • Pengfei Xue
  • Zhengyi Jiang
  • Qingsen Meng
Original Paper

Abstract

(TiB2–TiC)–Ni/TiAl/Ti functionally gradient materials were prepared by field-activated pressure-assisted synthesis processes. (TiB2–TiC)–Ni composite ceramic, the top layer of the functional gradient materials, was prepared in situ by the combustion synthesis process using Ti and B4C powders as raw materials. Scanning electron microscope (SEM) images of the ceramic layer revealed that the TiB2 and TiC particles in the composite were fine and homogeneously dispersed in the Ni matrix. The friction and wear properties of the (TiB2–TiC)–Ni ceramic were evaluated by sliding against a GCr15 disk at temperatures from ambient up to 400 °C. The experimental results showed that the friction coefficient of the (TiB2–TiC)–Ni ceramic decreased with the increasing testing temperature, load, and sliding speed. However, the loss rate decreased at higher temperature and increased at higher load and higher sliding speed. The wear mechanisms of (TiB2–TiC)–Ni ceramic mainly depend upon thermal oxidation at higher temperature, load, and sliding speed. The worn topography and phase component of the worn surfaces were analyzed using SEM, energy dispersive spectroscopy, and X-ray diffraction. The oxide films of Fe2O3, TiO2, and B2O3 formed during the friction process play an important role in lubrication, which results in a smaller friction coefficient.

Keywords

Borides Carbides Friction mechanisms Self lubrication friction Ceramic composite 

Notes

Acknowledgments

This study was supported by projects of the National Science Foundation of China (No. 50975190), Shanxi Province Science Foundation for Youth and Young Scientists Fund of the National Natural Science Foundation of China (51101111).

Conflict of interest

None.

Ethical Standards

The study has been performed in accordance with the ethical standards laid down in the 1964 Declaration of Helsinki. All the authors agree to submit the paper to Tribology Letters.

References

  1. 1.
    Rebelo de Figueiredo, M., Muratore, C., Franz, R., Chromik, R.R., Wahl, K.J., Voevodin, A.A., O’Sullivan, M., Lechthaler, M., Mitterer, C.: In situ studies of TiC11−xNx hard coating tribology. Tribol. Lett. 40, 365–373 (2010)CrossRefGoogle Scholar
  2. 2.
    Shaha, K.P., Pei, Y.T., Martinez-Martinez, D., De Hosson, J.Th.M.: Influence of surface roughness on the transfer film formation and frictional behavior of TiC/a–C nanocomposite coatings. Tribol. Lett. 41, 97–101 (2011)CrossRefGoogle Scholar
  3. 3.
    Du, B., Wang, X., Zou, Z.: Microstructure and tribological behavior of laser in situ synthesized TiC-reinforced Fe-based composite coatings. Tribol. Lett. 43, 295–301 (2011)CrossRefGoogle Scholar
  4. 4.
    Kumar, S., Chakraborty, M., Subramanya Sarma, V., Murty, B.S.: Tensile and wear behaviour of in situ Al–7Si/TiB2 particulate composites. Wear 265, 134–142 (2008)CrossRefGoogle Scholar
  5. 5.
    Kumar, S., Subramanya Sarma, V., Murty, B.S.: High temperature wear behavior of Al–4Cu–TiB2 in situ composites. Wear 268, 1266–1274 (2010)CrossRefGoogle Scholar
  6. 6.
    Wang, X.H., Zhang, M., Du, B.S.: Fabrication in situ TiB2–TiC–Al2O3 multiple ceramic particles reinforced Fe-based composite coatings by gas tungsten arc welding. Tribol. Lett. 41, 171–176 (2011)CrossRefGoogle Scholar
  7. 7.
    Akhtar, F.: Microstructure evolution and wear properties of in situ synthesized TiB and TiC reinforced steel matrix composites. J. Alloys Compd. 459, 491–497 (2008)CrossRefGoogle Scholar
  8. 8.
    Zhang, X., Yang, J., Ma, J., Hao, J., Bi, Q., Liang, Y., Liu, W.: The tribological behaviour of Fe–28Al–5Cr/TiC under liquid paraffine lubrication. Tribol. Lett. 45, 109–116 (2012)CrossRefGoogle Scholar
  9. 9.
    Sun, G.J., Wu, S.J., Su, G.C.: Research on impact wear resistance of in situ reaction TiCp/Fe composite. Wear 269, 285–290 (2010)CrossRefGoogle Scholar
  10. 10.
    Vallauri, D., Atias Adrian, I.C., Chrysanthou, A.: TiC–TiB2 composites: a review of phase relationships, processing and properties. J. Eur. Ceram. Soc. 28, 1697–1713 (2008)CrossRefGoogle Scholar
  11. 11.
    Zou, B., Shen, P., Gao, Z., Jiang, Q.: Combustion synthesis of TiCx–TiB2 composites with hypoeutectic, eutectic and hypereutectic microstructures. J. Eur. Ceram. Soc. 28, 2275–2279 (2008)CrossRefGoogle Scholar
  12. 12.
    Zhao, H., Cheng, Y.B.: Formation of TiB2–TiC composites by reactive sintering. Ceram. Int. 25, 353–358 (1999)CrossRefGoogle Scholar
  13. 13.
    Zhao, Z., Zhang, L., Song, Y., Wang, W., Liu, H.: Microstructures and properties of large bulk solidified TiC–TiB2 composites prepared by combustion synthesis under high gravity. Scripta Mater. 61, 281–284 (2009)CrossRefGoogle Scholar
  14. 14.
    Wang, Z.T., Zhou, X.H., Zhao, G.G.: Microstructure and formation mechanism of in situ TiC–TiB2/Fe composite coating. Trans. Nonferr. Met. Soc. China 18, 831–835 (2008)CrossRefGoogle Scholar
  15. 15.
    Li, B., Liu, Y., Li, J., Cao, H., He, L.: Effect of sintering process on the microstructures and properties of in situ TiB2–TiC reinforced steel matrix composites produced by spark plasma sintering. J. Mater. Process. Technol. 210, 91–95 (2010)CrossRefGoogle Scholar
  16. 16.
    Xu, C.L., Wang, H.Y., Yang, Y.F., Jiang, Q.C.: Effect of Al–P–Ti–TiC–Nd2O3 modifier on the micro-structure and mechanical properties of hypereutectic Al-20 wt% Si alloy. Mater. Sci. Eng. A 452, 341–346 (2007)CrossRefGoogle Scholar
  17. 17.
    Chen, S.P., Meng, Q.S., Zhao, J.F., Munir, Z.A.: Synthesis and characterization of TiB2–Ni–Ni3Al–CrNi alloy graded material by field-activated combustion. J. Alloys Compd. 476, 889–893 (2009)CrossRefGoogle Scholar
  18. 18.
    Chen, S.P., Meng, Q.S., Liu, W., Munir, Z.A.: Titanium diboride–nickel graded materials prepared by field-activated, pressure-assisted synthesis process. J. Mater. Sci. 44, 1121–1126 (2009)CrossRefGoogle Scholar
  19. 19.
    He, L., Zhang, X., Tong, C.: Surface modification of pure titanium treated with B4C at high temperature. Surf. Coat. Technol. 200, 3016–3020 (2006)CrossRefGoogle Scholar
  20. 20.
    Oh, D.Y., Kim, H.C., Yoon, J.K., Shon, I.J.: Simultaneous synthesis and consolidation process of ultra-fine WSi2–SiC and its mechanical properties. J. Alloys Compd. 386, 270–275 (2005)CrossRefGoogle Scholar
  21. 21.
    Yang, Z.L., Ouyang, J.H., Liu, Z.G., Liang, X.S.: Wear mechanisms of TiN–TiB2 ceramic in sliding against alumina from room temperature to 700 °C. Ceram. Int. 36, 2129–2135 (2010)CrossRefGoogle Scholar
  22. 22.
    Jianxin, D., Wenlong, S., Hui, Z., Pei, Y., Aihua, L.: Friction and wear behaviors of the carbide tools embedded with solid lubricants in sliding wear tests and in dry cutting processes. Wear 270, 666–674 (2011)CrossRefGoogle Scholar
  23. 23.
    Li, Y., Zou, Z., Feng, T., Wang, X.: Oxidation resistance and phase constituents in the brazing interface of WC–TiC–Co hard alloys. J. Mater. Process. Technol. 122, 51–55 (2002)CrossRefGoogle Scholar
  24. 24.
    Liu, N., Xu, Y.D., Li, H., Chen, M.H., Zhou, J., Xie, F., Yang, H.D.: Cutting and wearing characteristics of TiC-based cermets cutters with nano-TiN addition. J. Mater. Process. Technol. 161, 478–484 (2005)CrossRefGoogle Scholar
  25. 25.
    Jianxin, D., Hui, Z., Ze, W., Yunsong, L., Youqiang, X., Shipeng, L.: Unlubricated friction and wear behaviors of Al2O3/TiC ceramic cutting tool materials from high temperature tribological tests. Int. J. Refract. Met. Hard Mater. 35, 17–26 (2012)CrossRefGoogle Scholar
  26. 26.
    Jerome, S., Ravisankar, B., Mahato, P.K., Natarajan, S.: Synthesis and evaluation of mechanical and high temperature tribological properties of in situ Al–TiC composites. Tribol. Int. 43, 2029–2036 (2010)CrossRefGoogle Scholar
  27. 27.
    Guo, C., Zhou, J., Zhao, J., Wang, L., Youjun, Y., Chen, J., Zhou, H.: Microstructure and tribological properties of a HfB2-containing Ni-based composite coating produced on a pure Ti substrate by laser cladding. Tribol. Lett. 44, 187–200 (2011)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2012

Authors and Affiliations

  • Lifang Hu
    • 1
  • Shaoping Chen
    • 1
  • Pengfei Xue
    • 1
  • Zhengyi Jiang
    • 2
  • Qingsen Meng
    • 1
    • 2
  1. 1.College of Materials Science and EngineeringTaiyuan University of TechnologyTaiyuanChina
  2. 2.School of Mechanical, Materials and Mechatronic EngineeringUniversity of WollongongWollongongAustralia

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