Tribology Letters

, 44:229 | Cite as

Evolution of Tribological Properties of Reactor-Grade NiCr-B Coating

  • C. R. Das
  • N. Kumar
  • S. Dash
  • P. Chandramohan
  • M. P. Srinivasan
  • S. K. Albert
  • A. K. Tyagi
  • A. K. Bhaduri
  • Baldev Raj
Original Paper

Abstract

The tribological properties of reactor-grade NiCr-B hardfaced coating were studied at a constant load and sliding velocity. The objective of the present article is to investigate the changes in coefficient of friction that accompanies morphological and phase changes occurring in wear scars. Such changes result from the sliding with a spherical steel ball. The transition from the low to high coefficient of friction at higher sliding distance is attributed to severe cracking as well as fretting wear–induced deformation of surface oxide scales. Increased value of coefficient of friction arises from protracted sliding over longer distances continued to deform and detachment of weakly adhered oxides like Fe2O3 and Cr2O3. Such scales are tribochemically formed on the wear scars and contribute to alteration in the coefficient of friction. The evolution of oxide phases in wear scars is found to be one of the main mechanisms for dissipation of frictional force.

Keywords

NiCr-B Tribological properties Oxide scales Fatigue and fretting wear 

Notes

Acknowledgment

Mr. Ashok Bahuguna, IGCAR, is acknowledged for carrying out the dimensional measurements of wear tracks.

References

  1. 1.
    Bowden, F.P., Tabor, D.: The friction and lubrication of solids. Oxford University Press, Oxford (1954)Google Scholar
  2. 2.
    Bowden, F.P., Tabor, D.: The friction and lubrication of solids. Part II. Oxford University Press, Oxford (1964)Google Scholar
  3. 3.
    Rabinowicz, E.: Friction and wear of materials. John Wiley & Sons Inc., New York (1965)Google Scholar
  4. 4.
    Dwivedi, D.K.: Adhesive wear behaviour of cast aluminium–silicon alloys: overview. Mater. Design 31, 2517–2531 (2010)CrossRefGoogle Scholar
  5. 5.
    Prasad, B.K.: Structure–property related changes in hypoeutectic Al–Si alloys induced by solutionizing. Mater. Trans. JIM 34, 873–881 (1994)Google Scholar
  6. 6.
    Dwivedi, D.K., Sharma, A., Rajan, T.V.: Friction and wear behaviour of hypereutectic Al–Si base alloys at low sliding velocities. Trans. Ind. Inst. Met. 54, 247–254 (2001)Google Scholar
  7. 7.
    Mahanti, R.K., Lal, K., Sinha, A.N., Shivaramakrishanan, C.S.: A novel technique for hyper eutectic aluminium–silicon alloy melt treatment. Mater. Trans. JIM 34, 1207–1211 (1993)Google Scholar
  8. 8.
    Mohammeda, J.K., Dwarkadas, E.S.: Wear in Al–Si alloys under dry sliding conditions. Wear 119, 119–130 (1987)CrossRefGoogle Scholar
  9. 9.
    Huq, M.Z., Celis, J.P.: Expressing wear rate in sliding contacts based on dissipated energy. Wear 252, 375–383 (2002)CrossRefGoogle Scholar
  10. 10.
    Weston, D.P., Shipway, P.H., Harris, S.J., Cheng, M.K.: Friction and sliding wear behaviour of electrodeposited cobalt and cobalt–tungsten alloy coatings for replacement of electrodeposited chromium. Wear 267, 934–943 (2009)CrossRefGoogle Scholar
  11. 11.
    Ocken, H.: The galling wear resistance of new iron-base hardfacing alloys: a comparison with established cobalt- and nickel-base alloys. Surf. Coat. Technol. 76–77, 456–461 (1995)Google Scholar
  12. 12.
    Das, C.R., Albert, S.K., Bhaduri, A.K., Sudha, C., Terrance, A.L.E.: Characterisation of nickel based hardfacing deposits on austenitic stainless steel. Surf. Eng. 21, 29–290 (2005)CrossRefGoogle Scholar
  13. 13.
    Das, C.R., Albert, S.K., Bhaduri, A.K., Nithya, R.: Effect of dilution on microstructure and wear behaviour of NiCr hardface deposits. Mater. Sci. Technol. 23, 771–779 (2007)CrossRefGoogle Scholar
  14. 14.
    Mccarty, K.F., Boehme, D.R.: A Raman study of the systems Fe3−xCrxO4 and Fe2−xCrxO3*. J. Solid State Chem. 79, 19–27 (1989)CrossRefGoogle Scholar
  15. 15.
    Colmonoy Technical Data Sheet, Copyright Wall Colmonoy Corporation, 101 West Girard, Madison Hts., MI 48071-1880 (2008)Google Scholar
  16. 16.
    Cho, J., Xionga, Y., Kim, J., Lee, C., Hwang, S.Y.: Tribological behavior of NiCr-base blended and nanostructured composite APS coatings by rig test. Wear 265, 1565–1571 (2008)CrossRefGoogle Scholar
  17. 17.
    Stott, F.H.: The role of oxidation in the wear of alloys. Tribol. Int. 31, 61–67 (1998)CrossRefGoogle Scholar
  18. 18.
    Bedolla-Jacuinde, A., Aguilar, S.L., Maldonado, C.: Eutectic modification in a low chromium white cast iron by a mixture of titanium, rare earths, and bismuth: Part II. Effect on the wear behavior. J. Mater. Eng. Perform. 14, 301–306 (2005)CrossRefGoogle Scholar
  19. 19.
    So, H.: The mechanism of oxidational wear. Wear 184, 161–167 (1995)CrossRefGoogle Scholar
  20. 20.
    Srisrual, A., Coindeau, S., Galerie, A., Petit, J.-P., Wouters, Y.: Identification by photoelectrochemistry of oxide phases grown during the initial stages of thermal oxidation of AISI 441 ferritic stainless steel in air or in water vapour. Corrosion Sci. 51, 562–568 (2009)CrossRefGoogle Scholar
  21. 21.
    Rybiaka, R., Fouvrya, S., Bonnet, B.: Fretting wear of stainless steels under variable temperature conditions: introduction of a ‘composite’ wear law. Wear 268, 413–423 (2010)CrossRefGoogle Scholar
  22. 22.
    Chin, K.J., Zaidi, H., Mathia, T.: Oxide film formation in magnetized sliding steel/steel contact—analysis of the contact stress field and film failure mode. Wear 259, 477–481 (2005)Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • C. R. Das
    • 1
  • N. Kumar
    • 2
  • S. Dash
    • 2
  • P. Chandramohan
    • 3
  • M. P. Srinivasan
    • 3
  • S. K. Albert
    • 1
  • A. K. Tyagi
    • 2
  • A. K. Bhaduri
    • 1
  • Baldev Raj
    • 4
  1. 1.Material Technology DivisionIndira Gandhi Centre for Atomic ResearchKalpakkamIndia
  2. 2.Surface and Nanoscience DivisionIndira Gandhi Centre for Atomic ResearchKalpakkamIndia
  3. 3.Water Chemistry DivisionIndira Gandhi Centre for Atomic ResearchKalpakkamIndia
  4. 4.Indira Gandhi Centre for Atomic ResearchKalpakkamIndia

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