Advertisement

FeBeta||[Mn–Ce/Ce0.75Zr0.25O2 + FeBeta] Dual-Bed Catalyst for the Efficient Synergistic Removal of NOx, CO, C4H10, and NH3-Slip

  • Alina I. Mytareva
  • Dmitriy A. Bokarev
  • Galina N. Baeva
  • Alexey Yu. Belyankin
  • Alexander Yu. Stakheev
Original Paper
  • 1 Downloads

Abstract

A dual-bed catalytic system has been developed for the complex after treatment of diesel engine exhaust gases comprising nitrogen oxides, CO, hydrocarbons, and residual NH3 (NH3-slip) within wide temperature range. The system demonstrates effective NOx abatement at 200–500 °C. The upstream bed (FeBeta) is responsible for the selective catalytic reduction of NOx by ammonia (NH3-SCR) above ~ 300 °C, while the downstream bed ([Mn–Ce/CeO2–ZrO2 + FeBeta] combined catalyst) provides effective NOx abatement below 300 °C and total oxidation of CO, hydrocarbons, and NH3-slip.

Keywords

NH3-SCR NH3-slip oxidation CO oxidation Hydrocarbon oxidation Dual-bed catalyst Ceria–zirconia FeBeta 

References

  1. 1.
    Boningari T, Smirniotis PG (2016) Curr Opin Chem Eng 13:133–141CrossRefGoogle Scholar
  2. 2.
    Tsinoglou DN, Koltsakis GC, Peyton Jones JC (2002) Ind Eng Chem Res 41(5):1152–1165CrossRefGoogle Scholar
  3. 3.
    Kureti S, Weisweiler W, Hizbullah K (2003) Appl Catal B 43(3):281–291CrossRefGoogle Scholar
  4. 4.
    Dhal GC, Mohana D, Prasad R (2017) Catal Sci Technol 7(9):1803–1825CrossRefGoogle Scholar
  5. 5.
    Parks JE (2010) Science 327(5973):1584–1585CrossRefPubMedGoogle Scholar
  6. 6.
    Yoshida K, Makino S, Sumiya S, Muramatsu G, Helferich R (1989) SAE Technical Paper 892046Google Scholar
  7. 7.
    Matarrese R, Morandi S, Castoldi L, Villa P, Lietti L (2017) Appl Catal B 201:318–330CrossRefGoogle Scholar
  8. 8.
    Bueno-López A, Lozano-Castelló D, McCue AJ, Anderson JA (2016) Appl Catal B 198:266–275CrossRefGoogle Scholar
  9. 9.
    Castoldi L, Matarrese R, Lietti L, Forzatti P (2006) Appl Catal B 64(1–2):25–34CrossRefGoogle Scholar
  10. 10.
    Teraoka Y, Nakano K, Kagawa S, Shangguan WF (1995) Appl Catal B 5(3):L181–L185CrossRefGoogle Scholar
  11. 11.
    Fino D, Fino P, Saracco G, Specchia V (2003) Appl Catal B 43(3):243–259CrossRefGoogle Scholar
  12. 12.
    Li Q, Meng M, Tsubaki N, Li X, Li Z, Xie Y, Hu T, Zhang J (2009) Appl Catal B 91(1–2):406–415CrossRefGoogle Scholar
  13. 13.
    Shangguan WF, Teraoka Y, Kagawa S (1998) Appl Catal B 16(2):149–154CrossRefGoogle Scholar
  14. 14.
    Atribak I, Bueno-López A, García-García A (2008) J Catal 259(1):123–132CrossRefGoogle Scholar
  15. 15.
    Teraoka Y, Kanada K, Furukawa H, Moriguchi I, Kagawa S (2001) Chem Lett 30(7):604–605CrossRefGoogle Scholar
  16. 16.
    Stakheev A Yu, Baeva GN, Bragina GO, Teleguina NS, Kustov AL, Grill M, Thøgersen JR (2013) Top Catal 56(1–8):427–433CrossRefGoogle Scholar
  17. 17.
    Stakheev A Yu, Bokarev DA, Mytareva AI, Parsapur RK, Selvam P (2014) Mendeleev Commun 24(5):313–315CrossRefGoogle Scholar
  18. 18.
    Stakheev A Yu, Mytareva AI, Bokarev DA, Baeva GN, Krivoruchenko DS, Kustov AL, Grill M, Thøgersen JR (2015) Catal Today 258(Part I):183–189CrossRefGoogle Scholar
  19. 19.
    Kröcher O, Elsener M (2008) Ing Eng Chem Res 47(22):8588–8593CrossRefGoogle Scholar
  20. 20.
    Metkar PS, Harold MP, Balakotaiah V (2012) Appl Catal B 111–112:67–80CrossRefGoogle Scholar
  21. 21.
    Krivoruchenko DS, Telegina NS, Bokarev DA, Stakheev AYu (2015) Kinet Catal 56(6):741–746CrossRefGoogle Scholar
  22. 22.
    Sjövall H, Blint RJ, Gopinath A, Olsson LA (2009) Ind Eng Chem Res 49(1):39–52CrossRefGoogle Scholar
  23. 23.
    Schuler A, Votsmeier M, Kiwic P, Gieshoff J, Hautpmann W, Drochner A, Vogel H (2009) Chem Eng J 154(1–3):333–340CrossRefGoogle Scholar
  24. 24.
    Nedyalkova R, Kamasamudram K, Currier NW, Li J, Yezerets A, Olsson L (2013) J Catal 299:101–108CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.N.D. Zelinsky Institute of Organic Chemistry Russian Academy of SciencesMoscowRussia

Personalised recommendations