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Topics in Catalysis

, Volume 61, Issue 15–17, pp 1653–1664 | Cite as

Decontamination of 1,2-Dichloroethane DNAPL in Contaminated Groundwater by Polymer-Modified Zero-Valent Iron Nanoparticles

  • Ndumiso Vukile Mdlovu
  • Kuen-Song Lin
  • Sat Septian Dwitya
  • Chung-Yu Chen
  • Chao-Lung Chiang
Original Paper
  • 84 Downloads

Abstract

Remediation of dense non-aqueous phase liquids (DNAPLs) contaminants in groundwater has received considerable attention in the environmental field. Generally, DNAPLs can flow with groundwater and further infiltrate down to deeper aquitard zone that is difficult to be removed by pumping. The DNAPLs may also contaminate the soil and groundwater concurrently in the duration of flowing with groundwater slowly. In this study, remediation of 1,2-dichloroethane (1,2-DCE) in DNAPL contaminated groundwater was studied by a reductive reaction with polyethylenimine (PEI) surface-modified zero-valent iron nanoparticles (PEI-nZVI). The prepared PEI-nZVI was injected into upstream wells and reach the plume of DNAPLs down with the flowing groundwater. Moreover, nZVI was further characterized after field injection and 1-day reaction with the contaminants to assess its effectiveness for the on-site reduction of 1,2-DCE. After direct injection of PEI-nZVI into the contaminated plume, the concentrations of 1,2-DCE was significantly reduced. Moreover, the plume was decontaminated to nontoxic species onto the highly active nZVI. By using resistivity image profiling (RIP), the conductivity data of modified nZVI solution and sampled groundwater were similar. In addition, RIP can reveal complex subsurface DNAPLs structures by dense sampling of resistivity variation at shallow depth. Additionally, X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectroscopy studies indicated that after the reductive reaction, nZVI and PEI-nZVI were oxidized to Fe3O4. The interatomic distances for the reacted samples were 1.95 Å and 1.93 Å, respectively. The combined technique of floating surface-modified nZVI and RIP method would be economically and environmentally attractive.

Graphical Abstract

Keywords

Zero-valent iron nanoparticles Polyethylenimine DNAPLs Chemical reduction Injection method Decontamination Groundwater remediation 

Notes

Acknowledgements

The financial support of Ministry of Science and Technology (MOST), Taiwan (MOST 103-2621-M-155-001) is gratefully acknowledged. We also thank Prof. Y. W. Yang, Dr. J. F. Lee, and Dr. Jeng-Lung Chen from Taiwan National Synchrotron Radiation Research Center (NSRRC) for their help in the XANES/EXAFS experiments or data analyses. We finally thank Prof C.H. Yang from National Central University (NCU) who helped us with the Resistivity Image Profiling (RIP) experiments.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Ndumiso Vukile Mdlovu
    • 1
  • Kuen-Song Lin
    • 1
  • Sat Septian Dwitya
    • 1
  • Chung-Yu Chen
    • 1
  • Chao-Lung Chiang
    • 1
  1. 1.Department of Chemical Engineering and Materials Science/Environmental Technology Research CenterYuan Ze UniversityTaoyuanTaiwan, ROC

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