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Development of Silver Based Catalysts Promoted by Noble Metal M (M = Au, Pd or Pt) for Glycerol Oxidation in Liquid Phase

Abstract

The liquid-phase oxidation of glycerol was studied to obtain glycolic acid as a value-added molecule. The effect of metal addition to silver based catalyst was investigated under strong basic condition. The best catalytic performance was obtained over silver catalyst promoted with a small amount of platinum Ag95–Pt5/CeO2. Namely, the conversion close to 54% was reached after 5 h of reaction at 60 °C, with the selectivity to glycolic acid of 51%. Further increase in the amount of promotor (up to 50%) changed the reaction mechanism to product selectively the glyceric acid.

Graphical Abstract

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Acknowledgements

This work was performed, in partnership with the SAS PIVERT, within the frame of the French Institute for the Energy Transition (Institut pour la Transition Energétique (ITE) P.I.V.E.R.T. (http://www.institut-pivert.com) selected as an Investment for the Future (“Investissements d’Avenir”). This work was supported, as part of the Investments for the Future, by the French Government under the reference ANR-001-01.

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Correspondence to Mickaël Capron.

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Zaid, S., Skrzyńska, E., Addad, A. et al. Development of Silver Based Catalysts Promoted by Noble Metal M (M = Au, Pd or Pt) for Glycerol Oxidation in Liquid Phase. Top Catal 60, 1072–1081 (2017). https://doi.org/10.1007/s11244-017-0800-6

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Keywords

  • glycerol oxidation
  • silver based catalysts
  • glycolic acid