In this work the activity of ruthenium decorated carbon foam (Ru/CF) catalyst was studied in three phase hydrogenation reaction of d-xylose to d-xylitol. The developed catalyst was characterized by using scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, inductively coupled plasma optical emission spectrometry and nitrogen adsorption–desorption measurement. Kinetic measurements were carried out in a laboratory scale pressurized reactor (Parr®) assisted by SpinChem® rotating bed reactor (SRBR), at pre-defined conditions (40–60 bar H2 and 100–120 °C). The study on the influence of reaction conditions showed that the conversion rate and selectivity of hydrogenation reaction of d-xylose was significantly affected by temperature. These results have been proved by a competitive kinetics model which was found to describe the behavior of the novel system (Ru/CF catalyst used together with the SRBR) very well. Besides, it was revealed that the catalytic activity as well as the stability of our Ru/CF-SRBR is comparable with the commercial ruthenium decorated carbon catalyst (Ru/AC) under identical reaction conditions. Moreover, all steps from catalyst preparation and catalyst recycling as well as catalytic testing can be performed in an easy, fast and elegant manner without any loss of materials. Briefly, the developed Ru/CF catalyst used together with the SRBR could be used an excellent alternative for the conventional Raney nickel catalyst in a slurry batch reactor and offers an attractive concept with obvious industrial applicability.
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Holladay J, Bozell J, White J, Johnson D (2007) Top value-added chemicals from biomass. DOE Report PNNL 16983
Massoth D, Massoth G, Massoth IR, Laflamme L, Shi W, Hu C, Gu F (2006) The effect of xylitol on Streptococcus mutans in children. J Calif Dent Assoc 34(3):231–234
Takahashi Y, Takeda C, Seto I, Kawano G, Machida Y (2007) Formulation and evaluation of lactoferrin bioadhesive tablets. Int J Pharm 343(1):220–227
Sokmen A, Gunes G (2006) Influence of some bulk sweeteners on rheological properties of chocolate. LWT Food Sci Technol 39(10):1053–1058
Tathod AP, Dhepe PL (2014) Towards efficient synthesis of sugar alcohols from mono- and poly-saccharides: role of metals, supports & promoters. Green Chem 16(12):4944–4954
Research and Market (2014) Xylitol—a global market overview. http://www.researchandmarkets.com/reports/2846975/xylitol-a-global-market-overview. Accessed 24 Sept 2015
Mikkola J-P, Vainio H, Salmi T, Sjöholm R, Ollonqvist T, Väyrynen J (2000) Deactivation kinetics of Mo-supported Raney Ni catalyst in the hydrogenation of xylose to xylitol. Appl Catal A 196(1):143–155
Yadav M, Mishra DK, Hwang J-S (2012) Catalytic hydrogenation of xylose to xylitol using ruthenium catalyst on NiO modified TiO 2 support. Appl Catal A 425:110–116
Gallezot P, Nicolaus N, Fleche G, Fuertes P, Perrard A (1998) Glucose hydrogenation on ruthenium catalysts in a trickle-bed reactor. J Catal 180(1):51–55
Hernández-Mejía C, Raja E, Olivos-Suarez A, Gascon J, Greer HF, Zhou W, Rothenberg G, Shiju RN (2015) Ru/TiO2-catalysed hydrogenation of xylose: the role of crystal structure of the support. Catalysis Science & Technology 6(2):577–582
Mishra DK, Dabbawala AA, Park JJ, Jhung SH, Hwang J-S (2014) Selective hydrogenation of d-glucose to d-sorbitol over HY zeolite supported ruthenium nanoparticles catalysts. Catal Today 232:99–107
Luo C, Wang S, Liu H (2007) Cellulose conversion into polyols catalyzed by reversibly formed acids and supported ruthenium clusters in hot water. Angew Chem Int Ed 46(40):7636–7639
Pham TN, Samikannu A, Kukkola J, Rautio A-R, Pitkänen O, Dombovari A, Lorite GS, Sipola T, Toth G, Mohl M (2014) Industrially benign super-compressible piezoresistive carbon foams with predefined wetting properties: from environmental to electrical applications. Sci Rep 4:6933. doi:10.1038/srep06933
Coker AK (2001) Modeling of chemical kinetics and reactor design, vol 1. Gulf Professional Publishing, Houston
Eta V, Anugwom I, Virtanen P, Mäki-Arvela P, Mikkola J-P (2014) Enhanced mass transfer upon switchable ionic liquid mediated wood fractionation. Ind Crops Prod 55:109–115
Mallin H, Muschiol J, Byström E, Bornscheuer UT (2013) Efficient biocatalysis with immobilized enzymes or encapsulated whole cell microorganism by using the SpinChem reactor system. ChemCatChem 5(12):3529–3532
Chan HYH, Takoudis CG, Weaver MJ (1997) High-pressure oxidation of ruthenium as probed by surface-enhanced Raman and X-ray photoelectron spectroscopies. J Catal 172(2):336–345
Mun C, Ehrhardt J, Lambert J, Madic C (2007) XPS investigations of ruthenium deposited onto representative inner surfaces of nuclear reactor containment buildings. Appl Surf Sci 253(18):7613–7621
Kinoshita K, Bett JAS, Stonehart P (1975) Effects of gas-and liquid-phase environments on the sintering behavior of platinum catalysts. In: Kuczynski GC (ed) Sintering and catalysis. Springer, Boston, pp 117–132
Hassan SA (1974) Kinetics of sintering of unsupported platinum catalyst in nitrogen, oxygen and hydrogen atmospheres. J Appl Chem Biotechnol 24(9):497–503
Guisnet M, Magnoux P (2001) Organic chemistry of coke formation. Appl Catal A 212(1):83–96
Salmi T, Murzin DY, Mikkola J-P, Wärnå J, Mäki-Arvela P, Toukoniitty E, Toppinen S (2004) Advanced kinetic concepts and experimental methods for catalytic three-phase processes. Ind Eng Chem Res 43(16):4540–4550
Sifontes Herrera VA, Oladele O, Kordás K, Eränen K, Mikkola JP, Murzin DY, Salmi T (2011) Sugar hydrogenation over a Ru/C catalyst. J Chem Technol Biotechnol 86(5):658–668
Wisniak J, Hershkowitz M, Stein S (1974) Hydrogenation of xylose over platinum group catalysts. Ind Eng Chem Prod Res Dev 13(4):232–236
de Beeck BO, Dusselier M, Geboers J, Holsbeek J, Morré E, Oswald S, Giebeler L, Sels BF (2015) Direct catalytic conversion of cellulose to liquid straight-chain alkanes. Energy Environ Sci 8:230
Mikkola JP, Salmi T, Sjöholm R (1999) Modelling of kinetics and mass transfer in the hydrogenation of xylose over Raney nickel catalyst. J Chem Technol Biotechnol 74(7):655–662
Mishra DK, Dabbawala AA, Hwang JS (2013) Ruthenium nanoparticles supported on zeolite Y as an efficient catalyst for selective hydrogenation of xylose to xylitol. J Mol Catal A 376:63–70
SpinChem AB is thanked for providing the polymeric precursor materials and the SpinChem® rotating bed reactor. The Artificial Leaf, Bio4Energy programme & the Kempe Foundations are acknowledged for funding. This work is also a part of the ‘‘Artificial Leaf’’ project activities funded by the Knut & Alice Wallenberg foundation as well as the Johan Gadolin Process Chemistry Centre at Åbo Akademi University.
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Pham, T.N., Samikannu, A., Rautio, A. et al. Catalytic Hydrogenation of d-Xylose Over Ru Decorated Carbon Foam Catalyst in a SpinChem® Rotating Bed Reactor. Top Catal 59, 1165–1177 (2016) doi:10.1007/s11244-016-0637-4
- Carbon foam
- Rotating bed reactor