Topics in Catalysis

, Volume 60, Issue 3–5, pp 289–294 | Cite as

NO Adsorption and Reaction on Aged Pd–Rh Natural Gas Vehicle Catalysts: A Combined TAP and Steady-State Kinetic Approach

  • Pascal GrangerEmail author
  • Y. Renème
  • F. Dhainaut
  • Y. Schuurman
  • C. Mirodatos
Original Paper


A combined temporal analysis of products (TAP) and steady-state kinetic study was achieved to characterize the surface reactivity of fresh and aged bimetallic Pd–Rh/Al2O3 Natural-Gas Vehicle catalysts. Single NO pulse TAP experiments were performed on a stabilized surface after exposure to successive NO pulses until to get a steady-state NO conversion. Outlet flow curves recorded during such experiments show fast reaction steps taking place on noble metal particles and a slow process during NO desorption ascribed to the involvement of spill-over effect of chemisorbed NO molecules from the metal to the support. This slow process attenuates on the aged sample likely due to an alteration of the metal/support interface induced by particle sintering at high temperature. Thermal aging also alters the surface composition of bimetallic Pd–Rh particles which leads to changes in the products distribution from NO dissociation. A similar selectivity behavior is observed from steady-state kinetic measurements during the NO/H2 reaction. Interestingly, a weak partial pressure dependency of the selectivity reflects a surface Rh enrichment of Pd–Rh particles during aging.


Thermal aging TAP reactor NGV Pd–Rh catalyst NO adsorption DeNOx N2O formation 



We would like to thank the Ademe for a grant (Y. Renème). The laboratory participates in the Institut de Recherche en ENvironnement Industriel (IRENI) which is financed by the Communauté Urbaine de Dunkerque, the Région Nord Pas-de-Calais, the Ministère de l’Enseignement Supérieur et de la Recherche, the CNRS and European Regional Development Fund (ERDF).


  1. 1.
    Salaün M, Kouakou A, Da Costa A, Da Costa P (2009) Appl Catal B 88:386–397CrossRefGoogle Scholar
  2. 2.
    Klingstedt F, Neyestanaki AK, Byggningsbacka R, Lindfors LE, Lundén M, Petersson M, Tengström P, Ollonqvist T, Väyrynen J (2001) Appl Catal A 209:301–316CrossRefGoogle Scholar
  3. 3.
    Dhainaut F, Pietrzik S, Granger P (2007) Top Catal 42–43:135–141CrossRefGoogle Scholar
  4. 4.
    Renème Y, Dhainaut F, Granger P (2012) Appl Catal B 111–112:424–432CrossRefGoogle Scholar
  5. 5.
    Gelin P, Primet M (2009) Appl Catal B 39:1–37CrossRefGoogle Scholar
  6. 6.
    Gremminger AT, Pereira de Carvalho HW, Popescu R, Grunwaldt JD, Deutshmann O (2015) Catal Today 258:277–284 doi: 10.1016/j.cattod.2015.01.034 CrossRefGoogle Scholar
  7. 7.
    Granger P, Delannoy L, Leclercq L, Leclercq G (1998) J Catal 177:147–151CrossRefGoogle Scholar
  8. 8.
    Granger P, Malfoy P, Leclercq L, Leclercq L (2004) J Catal 223:142–151CrossRefGoogle Scholar
  9. 9.
    Granger P, Dhainaut F, Pietrzik S, Malfoy P, Mamede AS, Leclercq L, Leclercq G (2006) Top Catal 39:65–76CrossRefGoogle Scholar
  10. 10.
    Hibbits DD, Jiménez R, Yoshimura M, Weiss B, Iglesia E (2014) J Catal 319:95–109CrossRefGoogle Scholar
  11. 11.
    Frank B, Emig G, Renken A (1998) Appl Catal B 19:45–57CrossRefGoogle Scholar
  12. 12.
    Renème Y, Dhainaut F, Schuurman Y, Mirodatos C, Granger P (2014) Appl Catal B 160–161:390–399CrossRefGoogle Scholar
  13. 13.
    Gleaves JT, Yablonski GS, Phanawadee P, Schuurman Y (1997) Appl Catal A 160:55–88CrossRefGoogle Scholar
  14. 14.
    Dhainaut F, Pietrzik S, Granger P (2008) J Catal 258:296–305CrossRefGoogle Scholar
  15. 15.
    Dhainaut F, Pietrzik S, Granger P (2007) Appl Catal B 70:100–110CrossRefGoogle Scholar
  16. 16.
    Ng KYS, Belton DN, Schmieg SJS, Fisher GB (1994) J Catal 146:394–406CrossRefGoogle Scholar
  17. 17.
    Hu Z, Hallen FM, Wan CZ, Heck RM, Steger JJ, Lakis RE, Lyman CE (1998) J Catal 174:13–21CrossRefGoogle Scholar
  18. 18.
    Granger P, Lecomte JJ, Dathy C, Leclercq L, Leclercq G (1998) J Catal 175:194–203CrossRefGoogle Scholar
  19. 19.
    Peden CHF, Belton DN, Schmieg SJJ (1995) J Catal 155:204–218CrossRefGoogle Scholar
  20. 20.
    Granger P, Lecomte JJ, Dathy C, Leclercq L, Leclercq G (1998) J Catal 173:304–31415CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Pascal Granger
    • 1
    Email author
  • Y. Renème
    • 1
  • F. Dhainaut
    • 1
  • Y. Schuurman
    • 2
  • C. Mirodatos
    • 2
  1. 1.Unité de Catalyse et de Chimie du Solide, ENSCL, UMR CNRS 8181Université Lille 1 Sciences et TechnologiesVilleneuve d’AscqFrance
  2. 2.Ircelyon, CNRSUniversité Lyon 1LyonFrance

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