Microwave Cavity Perturbation Studies on H-form and Cu Ion-Exchanged SCR Catalyst Materials: Correlation of Ammonia Storage and Dielectric Properties
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Ammonia-based selective catalytic reduction (SCR) has become the major control strategy for NOx emissions from light and heavy duty diesel engines. Before reducing NOx on the SCR active material, ammonia storage on the active sites of the catalyst is crucial. The in operando measurement of the dielectric properties of the catalyst material using microwave cavity perturbation is a promising indicator of ammonia loading. In this work, the influence of copper ion-exchange of the zeolite-based SCR material ZSM-5 on the NH3 storage and the dielectric properties is highlighted. The catalyst powder samples were monitored by microwave cavity perturbation as a function of the stored ammonia content at a frequency of approximately 1.2 GHz in a temperature range between 200 and 350 °C. Due to ion exchange, the NH3 storage behavior changes, what could be monitored in the sensitivity of the dielectric permittivity to NH3. The dependence of the complex dielectric permittivity on ammonia loading is decreased by ion exchange, hinting that mostly ammonia storage on Brønsted sites affects the dielectric permittivity. This finding adds new knowledge to the electrical conduction and polarization mechanisms occurring in these zeolite materials.
KeywordsNH3 storage Microwaves Cavity perturbation Zeolites ZSM-5
R.M. is indebted to the German Research Foundation (DFG) for supporting this work under grant MO 1060/19-1.U.S. acknowledges financial supported by the German Research Foundation (DFG), contract No: Si609/14-1, and by the Exploratory Research Space of RWTH Aachen University within the Center for Automotive Catalytic Systems Aachen (ACA).A.P. acknowledges the support of Merck GKaA.
- 10.Janssens TVW, Falsig H, Lundegaard LF, Vennestrøm PNR, Rasmussen SB, Moses PG, Giordanino F, Borfecchia E, Lomachenko KA, Lamberti C, Bordiga S, Godiksen A, Mossin S, Beato P (2015) A consistent reaction scheme for the selective catalytic reduction of nitrogen oxides with ammonia. ACS Catal. doi: 10.1021/cs501673g Google Scholar
- 17.Kulkarni VP, Leustek ME, Michels SK, Nair RN, Snopko MA, Knitt AA (2013) Ash detection in diesel particulate filter. U.S. Patent 8,470,070 B2Google Scholar