Topics in Catalysis

, Volume 58, Issue 7–9, pp 405–409 | Cite as

Heterogeneous Catalysis for the Conversion of Sugars into Polymers

Original Paper

Abstract

The synthesis of commodity polymers from biomass presents interesting challenges and opportunities for new catalytic chemistries. Starting from glucose, reaction pathways to a variety of monomers for commodity polymers are presented. The first step for each pathway is the isomerization of glucose to fructose. This reaction can now be accomplished in aqueous media with hydrophobic, large pore molecular sieves that contain Lewis acid sites as catalysts. A typical catalyst is a pure-silica molecular sieve having the zeolite beta topology and containing a small amount of framework Sn4+ (Sn-Beta). Dehydration of fructose into 5-hydroxymethylfurfural (HMF) provides a convenient path that can lead to 2,5-furandicarboxylic acid (FDCA) for the synthesis of polyethylene furanoate (PEF) or purified terephthalic acid (PTA) (via Diels–Alder reactions) for the synthesis of polyethylene terephthalate (PET). Recent progress on the dehydration of lactic acid could open new routes to acrylic acid and acrylonitrile that are used to produce polyacrylic acid and polyacrylonitrile, respectively, provided more selective catalysts for the retro-aldol deconstruction of fructose are developed.

Keywords

Sugars Monomers Heterogeneous catalysis Biomass 

References

  1. 1.
    Corma A, Iborra S, Velty A (2007) Chem Rev 107:2411–2502CrossRefGoogle Scholar
  2. 2.
    Dusselier M, Van Wouwe P, Dewaele A, Makshina E, Sels BF (2013) Energy Environ Sci 6:1415–1442CrossRefGoogle Scholar
  3. 3.
    Vennestrom PNR, Osmundsen CM, Christensen CH, Taarning E (2011) Angew Chem Int Ed 50:10502–10509CrossRefGoogle Scholar
  4. 4.
    www.braskem.com.br. Accessed 2014
  5. 5.
    Moliner M, Roman-Leshkov Y, Davis ME (2010) Proc Natl Acad Sci USA 107:6164–6168CrossRefGoogle Scholar
  6. 6.
    Bermejo-Deval R, Assary RS, Nikolla E, Moliner M, Roman-Leshkov Y, Hwang SJ, Palsdottir A, Silverman D, Lobo RF, Curtiss LA, Davis ME (2012) Proc Natl Acad Sci USA 109:9727–9732CrossRefGoogle Scholar
  7. 7.
    Bermejo-Deval R, Orazov M, Gounder R, Hwang SJ, Davis ME (2014) ACS Catal 4:2288–2297CrossRefGoogle Scholar
  8. 8.
    Raj N, Caratzoulas S, Vlachos DG (2013) ACS Catal 3:2294–2298CrossRefGoogle Scholar
  9. 9.
    Rajabbeigi N, Torres AI, Lew CM, Elyassi B, Ren L, Wang Z, Cho HJ, Fan W, Daoutidis P, Tsapatsis M (2014) Chem Eng Sci 116:235–242CrossRefGoogle Scholar
  10. 10.
    Zhao H, Holladay JE, Brown H, Zhang ZC (2007) Science 316:1597–1600CrossRefGoogle Scholar
  11. 11.
    Takagaki A, Ohara M, Nishimura S, Ebitani K (2009) Chem Commun 194:6276–6278CrossRefGoogle Scholar
  12. 12.
    Nakajima K, Noma R, Kitano M, Hara M (2014) J Mol Catal A 388–389:100–105CrossRefGoogle Scholar
  13. 13.
    Nikolla E, Roman-Leshkov Y, Moliner M, Davis ME (2011) ACS Catal 1:408–410CrossRefGoogle Scholar
  14. 14.
    www.ava-biochem.com. Accessed 2014
  15. 15.
    www.avantium.com. Accessed 2014
  16. 16.
    Masuno M, Cannon D, Bissell J, Smith RL, Foster M, Wood AB, Smith PB, Hucul DA WO 2013/040514 A1Google Scholar
  17. 17.
    Chang CC, Green SK, Williams CL, Dauenhauer P, Fan W (2014) Green Chem 16:585–588CrossRefGoogle Scholar
  18. 18.
    Lin Z, Ierapetritou M, Nikolakis V (2013) AIChE J 59:2079–2087CrossRefGoogle Scholar
  19. 19.
    Pacheco JJ, Davis ME (2014) Proc Natl Acad Sci USA 111:8363–8367CrossRefGoogle Scholar
  20. 20.
    Casanova O, Iborra S, Corma A (2009) ChemSusChem 2:1138–1144CrossRefGoogle Scholar
  21. 21.
    Yan B, Tao LZ, Liang Y, Xu BQ (2014) ACS Catal 4:1931–1943CrossRefGoogle Scholar
  22. 22.
    Peng J, Li X, Tang C, Bai W (2014) Green Chem 16:108–111CrossRefGoogle Scholar
  23. 23.
    Holm MS, Saravanamurugan S, Taarning E (2010) Science 328:602–605CrossRefGoogle Scholar
  24. 24.
    Lobo RF (2010) ChemSusChem 3:1237–1240CrossRefGoogle Scholar
  25. 25.
    Bermejo-Deval R PhD Thesis, California Institute of Technology, 2014Google Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  1. 1.Chemical EngineeringCalifornia Institute of TechnologyPasadenaUSA

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