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Topics in Catalysis

, Volume 57, Issue 17–20, pp 1550–1557 | Cite as

Aqueous Heck Arylation of Acrolein Derivatives: The Role of Cyclodextrin as Additive

  • Walid Al-Maksoud
  • Mohamad Jahjah
  • Eric Monflier
  • Anne Ponchel
  • Bastien Léger
  • Catherine Pinel
  • Laurent Djakovitch
Original Paper
  • 241 Downloads

Abstract

Heck arylation of acrolein dialkyl acetal with (hetero)-aryl halides in water catalyzed by solid palladium catalysts and in presence of cyclodextrins is reported. Depending on the nature of the base, either cinnamaldehyde or 3-aryl propionic ester is obtained. It was shown that the presence of cyclodextrins in the reaction media increased the reaction rate as well as the stability of the palladium species.

Keywords

Heck reaction Aqueous phase Cyclodextrins Heterogeneous palladium catalyst Cinnamaldehyde 3-Arylpropionic esters 

Notes

Acknowledgments

The authors gratefully acknowledge the National Agency of Research (CATAQ N° ANR-07-CP2D-0167-01/02) for funding.

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Walid Al-Maksoud
    • 1
  • Mohamad Jahjah
    • 1
  • Eric Monflier
    • 2
  • Anne Ponchel
    • 2
  • Bastien Léger
    • 2
  • Catherine Pinel
    • 1
  • Laurent Djakovitch
    • 1
  1. 1.Université de Lyon, CNRS, UMR 5256, IRCELYON, Institut de recherches sur la catalyse et l’environnement de LyonVilleurbanneFrance
  2. 2.Université d’Artois, UMR CNRS 8181, UCCS Artois, Faculté des Sciences Jean PerrinLens CedexFrance

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