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Topics in Catalysis

, Volume 57, Issue 17–20, pp 1483–1489 | Cite as

Bifunctional Catalyst Control of Alkene Isomerization

  • Douglas B. GrotjahnEmail author
  • Casey R. Larsen
  • Gulin Erdogan
Article

Abstract

The ability to control the formation and chemistry of alkenes is of central importance to organic synthesis in both industry and academia. Progress in using catalysts with bifunctional (heteroaryl)phosphines to control positional and/or geometric selectivity in alkene isomerization and related chemistry is summarized.

Keywords

Alkene Isomerization Bifunctional Phosphine Selectivity 

Notes

Acknowledgments

SDSU colleague Professor Andrew L. Cooksy is thanked for his invaluable role as co-author on many our papers on bifunctional catalysis and co-P.I. on Grants. Dr. LeRoy Lafferty has assisted the author and his students with NMR experiments. Professor Arnold Rheingold and his group have been invaluable for their X-ray diffraction expertise. The NSF is thanked for support of our research on bifunctional catalysis through Grants CHE-1059107, 0719575, and 0415783, and for an award upgrading the SDSU departmental NMR facility (MRI CHE-0521698).The San Diego Foundation is thanked for support by a Blasker award in 2006–2007.

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Douglas B. Grotjahn
    • 1
    Email author
  • Casey R. Larsen
    • 1
  • Gulin Erdogan
    • 1
  1. 1.Department of Chemistry and BiochemistrySan Diego State UniversitySan DiegoUSA

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