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Pt-supported Spherical Mesoporous Silica as a Nanosized Catalyst for Efficient Liquid-Phase Hydrogenation

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Abstract

Mesoporous silica nanospheres with an average diameter of approximately 240 and 600 nm have been used as catalyst supports of active Pt nanoparticles, which were found to be highly efficient for liquid-phase hydrogenation under atmospheric H2 compared to the micron-sized conventional mesoporous silica because of the suppression of mass-transport limitation toward active sites.

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References

  1. 1.

    Mori K, Yamashita H (2010) Phys Chem Chem Phys 12:14420

  2. 2.

    Mori K, Yamashita H (2011) J Jpn Petrol Inst 54:1

  3. 3.

    Yamashita H, Mori K (2007) Chem Lett 36:348

  4. 4.

    Li W, Zhao D (2013) Chem Commun 49:943

  5. 5.

    Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS (1992) Nature 359:710

  6. 6.

    Cheng C-F, Luan Z, Klinowski J (1995) Langmuir 11:2815

  7. 7.

    Fuku K, Hayashi R, Takakura S, Kamegawa T, Mori K, Yamashita H (2013) Angew Chem Inter Ed 52:7446

  8. 8.

    Mori K, Furubayashi K, Okada S, Yamashita H (2012) Chem Commun 48:8886

  9. 9.

    Fuku K, Takakura S, Kamegawa T, Mori K, Yamashita H (2012) Chem Lett 41:614

  10. 10.

    Fuku K, Sakano T, Kamegawa T, Mori K, Yamashita H (2012) J Mater Chem 22:16243

  11. 11.

    Nakasaka Y, Tago T, Yano K, Masuda T (2010) Chem Eng Sci 65:226

  12. 12.

    Tago T, Nakasaka Y, Masuda T (2012) J Jpn Petrol Inst 55:149

  13. 13.

    Coasne B, Galarneau A, Di Renzo F, Pellenq RJM (2006) Langmuir 22:11097

  14. 14.

    Tsai F-Y, Wu C-L, Mou C-Y, Chao M-C, Lin H-P, Liu S-T (2004) Tetrahedron Lett 45:7503

  15. 15.

    Suzuki TM, Nakamura T, Sudo E, Akimoto Y, Yano K (2008) Micropor Mesopor Mater 111:350

  16. 16.

    Okada S, Urata T, Kamegawa T, Mori K, Yamashita H (2011) Chem Lett 40:609

  17. 17.

    Okada S, Ikurumi S, Kamegawa T, Mori K, Yamashita H (2012) J Phys Chem C 116:14360

  18. 18.

    Okada S, Mori K, Kamegawa T, Che M, Yamashita H (2011) Chem Eur J 17:9047

  19. 19.

    Mori K, Watanabe K, Kawashima M, Che M, Yamashita H (2010) J Phys Chem C 115:1044

  20. 20.

    Mori K, Tottori M, Watanabe K, Che M, Yamashita H (2011) J Phys Chem C 115:21358

  21. 21.

    Mori K, Watanabe K, Terai Y, Fujiwara Y, Yamashita H (2012) Chem Eur J 18:11371

  22. 22.

    Kamegawa T, Suzuki N, Che M, Yamashita H (2011) Langmuir 27:2873

  23. 23.

    Du X, He J (2011) Nanoscale 3:3984

  24. 24.

    Cauda V, Schlossbauer A, Kecht J, Zürner A, Bein T (2009) J Am Chem Soc 131:11361

  25. 25.

    Grün M, Unger KK, Matsumoto A, Tsutsumi K (1999) Micropor Mesopor Mater 27:207

  26. 26.

    Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW (1992) J Am Chem Soc 114:10834

  27. 27.

    Yamada Y, Yano K (2006) Micropor Mesopor Mater 93:190

  28. 28.

    Mori K, Ogawa S, Martis M, Yamashita H (2012) J Phys Chem C 116:18873

  29. 29.

    Mori K, Kumami A, Tomonari M, Yamashita H (2009) J Phys Chem C 113:16850

  30. 30.

    Mori K, Kumami A, Yamashita H (2011) Phys Chem Chem Phys 13:15821

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Acknowledgments

This work was supported by the Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology of Japan (237607430). A part of this work was also performed under a management of ‘Elements Strategy Initiative for Catalysts & Batteries (ESICB) supported by MEXT. XAFS spectra were recorded using a fluorescence-yield collection technique at the beam line 01B1 station with an attached Si (311) monochromator at SPring-8, JASRI, Harima, Japan (prop. Nos. 2012A1061 and 2012B1058). The author appreciates Dr. Eiji Taguchi at the Research Center for Ultra-High Voltage Electron Microscopy, Osaka University for assistance with TEM measurements.

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Correspondence to Kohsuke Mori or Hiromi Yamashita.

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Mori, K., Urata, T., Okada, S. et al. Pt-supported Spherical Mesoporous Silica as a Nanosized Catalyst for Efficient Liquid-Phase Hydrogenation. Top Catal 57, 1026–1031 (2014). https://doi.org/10.1007/s11244-014-0266-8

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Keywords

  • Mesoporous silica
  • Spherical nanocatalyst
  • Hydrogenation
  • Platinum