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Topics in Catalysis

, Volume 57, Issue 6–9, pp 723–729 | Cite as

Gold-Based Nanoparticulate Catalysts for the Oxidative Esterification of 1,4-Butanediol to Dimethyl Succinate

  • Gemma L. Brett
  • Peter J. Miedziak
  • David W. Knight
  • Stuart H. Taylor
  • Graham J. HutchingsEmail author
Original Paper

Abstract

The effect of the reaction conditions and catalyst composition on the oxidation of 1,4-butanediol has been investigated. We have shown that gold and gold–palladium nanoparticles supported on titania can be effective catalysts for this oxidation reaction. We have demonstrated that the formation of butyrolactone, methyl-4-hydroxybutyrate and dimethyl succinate follow a sequential reaction pathway. We have also investigated the role of acid/base on the reaction and have shown a beneficial synergistic effect of alloying gold with palladium on both the conversion and selectivity towards dimethyl succinate.

Keywords

Gold Palladium Alloys Titania Nanoparticles Oxidative esterification 

References

  1. 1.
    Huang J, Dai W-L, Fan K (2009) J Catal 266:228–235CrossRefGoogle Scholar
  2. 2.
    Zhu Y-L, Yang J, Dong G-Q, Zheng H-Y, Zhang H–H, Xiang H-W, Li Y-W (2005) Appl Catal B 57:183–190CrossRefGoogle Scholar
  3. 3.
    Ichikawa N, Sato S, Takahashi R, Sodesawa T, Inui K (2004) J Mol Catal A Chem 212:197–203CrossRefGoogle Scholar
  4. 4.
    Huang J, Dai W-L, Li H, Fan K (2007) J Catal 252:69–76CrossRefGoogle Scholar
  5. 5.
    Haruta M, Uphade B, Tsubota S, Miyamoto A (1998) Res Chem Intermed 24:329–336CrossRefGoogle Scholar
  6. 6.
    Golunski S, Rajaram R, Hodge N, Hutchings GJ, Kiely CJ (2002) Catal Today 72:107–113CrossRefGoogle Scholar
  7. 7.
    Solsona BE, Garcia T, Jones C, Taylor SH, Carley AF, Hutchings GJ (2006) Appl Catal A 312:67–76CrossRefGoogle Scholar
  8. 8.
    Biella S, Rossi M (2003) Chem Commun 28:378–379CrossRefGoogle Scholar
  9. 9.
    Porta F, Prati L (2004) J Catal 224:397–403CrossRefGoogle Scholar
  10. 10.
    Dimitratos N, Lopez-Sanchez JA, Anthonykutty JM, Brett G, Carley AF, Tiruvalam RC, Herzing AA, Kiely CJ, Knight DW, Hutchings GJ (2009) Phys Chem Chem Phys 11:4952–4961CrossRefGoogle Scholar
  11. 11.
    Bianchi CL, Canton P, Dimitratos N, Porta F, Prati L (2005) Catal Today 102–103:203–212CrossRefGoogle Scholar
  12. 12.
    Enache DI, Edwards JK, Landon P, Solsona-Espriu B, Carley AF, Herzing AA, Watanabe M, Kiely CJ, Knight DW, Hutchings GJ (2006) Science 311:362–365CrossRefGoogle Scholar
  13. 13.
    Miedziak PJ, He Q, Edwards JK, Taylor SH, Knight DW, Tarbit B, Kiely CJ, Hutchings GJ (2011) Catal Today 163:47–54CrossRefGoogle Scholar
  14. 14.
    Kondrat SA, Shaw G, Freakley SJ, He Q, Hampton J, Edwards JK, Miedziak PJ, Davies TE, Carley AF, Taylor SH, Kiely CJ, Hutchings GJ (2012) Chem Sci 3:2965–2971CrossRefGoogle Scholar
  15. 15.
    Porta F, Prati L, Rossi M, Coluccia S, Martra G (2000) Catal Today 61:165–172CrossRefGoogle Scholar
  16. 16.
    Dimitratos N, Lopez-Sanchez JA, Meenakshisundaram S, Anthonykutty JM, Brett G, Carley AF, Taylor SH, Knight DW, Hutchings GJ (2009) Green Chem 11:1209–1216CrossRefGoogle Scholar
  17. 17.
    Prati L, Villa A, Porta F, Wang D, Su D (2007) Catal Today 122:386–390CrossRefGoogle Scholar
  18. 18.
    Hou W, Dehm NA, Scott RWJ (2008) J Catal 253:22–27CrossRefGoogle Scholar
  19. 19.
    Brett GL, Miedziak PJ, Dimitratos N, Lopez-Sanchez JA, Dummer NF, Tiruvalam R, Kiely CJ, Knight DW, Taylor SH, Morgan DJ, Carley AF, Hutchings GJ (2011) Catal Sci Technol 2:1914–1924Google Scholar
  20. 20.
    Kotionova T, Lee C, Miedziak P, Dummer N, Willock D, Carley A, Morgan D, Knight D, Taylor S, Hutchings G (2012) Catal Lett 142:1114–1120CrossRefGoogle Scholar
  21. 21.
    Carrettin S, McMorn P, Johnston P, Griffin K, Kiely CJ, Hutchings GJ (2003) Phys Chem Chem Phys 5:1329–1336CrossRefGoogle Scholar
  22. 22.
    Nielsen I, Taarning E, Egeblad K, Madsen R, Christensen C (2007) Catal Lett 116:35–40CrossRefGoogle Scholar
  23. 23.
    Hayashi T, Inagaki T, Itayama N, Baba H (2006) Catal Today 117:210–213CrossRefGoogle Scholar
  24. 24.
    Taarning E, Madsen AT, Marchetti JM, Egeblad K, Christensen CH (2008) Green Chem 10:408–414CrossRefGoogle Scholar
  25. 25.
    Yamamoto N, Obora Y, Ishii Y (2011) J Org Chem 76:2937–2941CrossRefGoogle Scholar
  26. 26.
    World Gold Council (2003) Gold Bull 36:24Google Scholar
  27. 27.
    Lopez-Sanchez JA, Dimitratos N, Miedziak P, Ntainjua E, Edwards JK, Morgan D, Carley AF, Tiruvalam R, Kiely CJ, Hutchings GJ (2008) Phys Chem Chem Phys 10:1921–1930CrossRefGoogle Scholar
  28. 28.
    Brett GL, He Q, Hammond C, Miedziak PJ, Dimitratos N, Sankar M, Herzing AA, Conte M, Lopez-Sanchez JA, Kiely CJ, Knight DW, Taylor SH, Hutchings GJ (2011) Angew Chem Int Ed 50:10136–10139CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • Gemma L. Brett
    • 1
  • Peter J. Miedziak
    • 1
  • David W. Knight
    • 1
  • Stuart H. Taylor
    • 1
  • Graham J. Hutchings
    • 1
    Email author
  1. 1.Cardiff Catalysis Institute, School of ChemistryCardiff UniversityCardiffUK

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