Topics in Catalysis

, Volume 57, Issue 6–9, pp 607–611 | Cite as

NiO as an Efficient Counter Electrode Catalyst for Dye-Sensitized Solar Cells

Original Paper


NiO is an important heterogeneous catalyst employed in chemical processes. However, it is a new topic to explore NiO as a counter electrode catalyst for dye-sensitized solar cells (DSSCs). In this paper, NiO with poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) was demonstrated an efficient DSSC counter electrode with a maximum power conversion efficiency of 7.58 %. Furthermore, electrochemical impedance spectroscopy and cyclic voltammetry measurements revealed that the excellent photovoltaic performance is due to the combination between the high catalytic activity of NiO and the superior electrical conductivity of PEDOT:PSS. The optimum weight ratio of NiO to PEDOT:PSS is 48.


Nickel oxide (NiO) Electrode catalysts Dye-sensitized solar cells (DSSC) 


  1. 1.
    Grätzel M (2003) J Photochem Photobiol C 4:145CrossRefGoogle Scholar
  2. 2.
    Law M, Greene LE, Johnson JC, Saykally R, Yang PD (2005) Nat Mater 4:455CrossRefGoogle Scholar
  3. 3.
    Hagfeldt A, Boschloo G, Sun L, Kloo L, Pettersson H (2010) Chem Rev 110:6595CrossRefGoogle Scholar
  4. 4.
    Yella A, Lee HW, Tsao HN, Yi C, Chandiran AK, Nazeeruddin K, Diau EWG, Yeh CY, Zakeeruddin SM, Grätzel M (2011) Science 334:629CrossRefGoogle Scholar
  5. 5.
    Bach U, Lupo D, Comte P, Moser JE, Weissörtel F, Salbeck J, Spreitzer H, Grätzel M (1998) Nature 395:583CrossRefGoogle Scholar
  6. 6.
    Mende LS, Bach U, Humphry-Baker R, Horiuchi T, Miura H, Ito S, Uchida S, Grätzel M (2005) Adv Mater 17:813CrossRefGoogle Scholar
  7. 7.
    Wang H, Hu YH (2012) Energy Environ Sci 5:8182CrossRefGoogle Scholar
  8. 8.
    Wang H, Wei W, Hu YH (2013) J Mater Chem A 1:6622CrossRefGoogle Scholar
  9. 9.
    Li GR, Wang F, Jiang QW, Gao XP, Shen PW (2010) Angew Chem Inter Ed 49:3653CrossRefGoogle Scholar
  10. 10.
    Han J, Kim H, Kim DY, Jo SM, Jang SY (2010) ACS Nano 4:3503CrossRefGoogle Scholar
  11. 11.
    Chen L, Tanb W, Zhang J, Zhou X, Zhang X, Lin Y (2010) Electrochim Acta 55:3721CrossRefGoogle Scholar
  12. 12.
    Hu YH, Ruckenstein E (2004) Adv Catal 48:297Google Scholar
  13. 13.
    Hu YH, Ruckenstein E (1998) J Phys Chem A 102:10568Google Scholar
  14. 14.
    Hu YH, Ruckenstein E (2002) Catal Rev 44:423CrossRefGoogle Scholar
  15. 15.
    Hu YH, Ruckenstein E (1998) J Phys Chem B 102:230Google Scholar
  16. 16.
    He JJ, Lindström H, Hagfeldt A, Lindquist SE (1999) J Phys Chem B 103:8940CrossRefGoogle Scholar
  17. 17.
    Li L, Gibson AE, Qin P, Boschloo G, Gorlov M, Hagfeldt A, Sun L (2010) Adv Mater 22:1759CrossRefGoogle Scholar
  18. 18.
    Nattestad A, Ferguson M, Kerr R, Cheng YB, Bach U (2008) Nanotechnology 19:295304CrossRefGoogle Scholar
  19. 19.
    Gibson AE, Smeigh LA, Pleux LL, Fortage J, Boschloo G, Blart E, Pellegrin Y, Odobel F, Hagfeldt A, Hammarström L (2009) Angew Chem Int Ed 48:4402CrossRefGoogle Scholar
  20. 20.
    Bandara J, Weerasinghe H (2005) Solar Energy Mater Solar Cells 85:385CrossRefGoogle Scholar
  21. 21.
    Guai GH, Leiw MY, Ng CM, Li CM (2012) Adv Energy Mater 2:334CrossRefGoogle Scholar
  22. 22.
    Bajpai R, Roy S, Koratkar N, Misra DS (2013) Carbon 56:56CrossRefGoogle Scholar
  23. 23.
    Okumura T, Sugiyo T, Inoue T, Ikegami M, Miyasaka T (2013) J Electrochem Soc 160:H155CrossRefGoogle Scholar
  24. 24.
    Gong F, Wang H, Xu X, Zhou G, Wang ZS (2012) J Am Chem Soc 134:10953CrossRefGoogle Scholar
  25. 25.
    Yeh MH, Lin LY, Lee CP, Wei HY, Chen CY, Wu CG, Vittal R, Ho KC (2011) J Mater Chem 21:19021CrossRefGoogle Scholar
  26. 26.
    Li GR, Wang F, Song J, Xiong FY, Gao XP (2012) Electrochim Acta 65:216CrossRefGoogle Scholar
  27. 27.
    Sakurai S, Jiang HQ, Takahashi M, Kobayashi K (2009) Electrochim Acta 54:5463CrossRefGoogle Scholar
  28. 28.
    Han LY, Koide N, Chiba Y, Islam A, Komiya R, Fuke N, Fukui A, Yamanaka R (2005) Appl Phys Lett 86:213501CrossRefGoogle Scholar
  29. 29.
    Joshi P, Zhang LF, Chen QL, Galipeau D, Fong H, Qiao Q (2010) ACS Appl Mater Interfaces 2:3572CrossRefGoogle Scholar
  30. 30.
    Koh JK, Kim J, Kim B, Kim JH, Kim E (2011) Adv Mater 23:1641CrossRefGoogle Scholar
  31. 31.
    Xia JB, Chen L, Yanagida SJ (2011) Mater Chem 21:4644CrossRefGoogle Scholar
  32. 32.
    Hauch A, Georg A (2001) Electrochim Acta 46:3457CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  1. 1.Department of Materials Science and EngineeringMichigan Technological UniversityHoughtonUSA

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