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Topics in Catalysis

, Volume 56, Issue 9–10, pp 765–769 | Cite as

Etherification of 5-Hydroxymethylfurfural to a Biodiesel Component Over Ionic Liquid Modified Zeolites

  • Eero Salminen
  • Narendra Kumar
  • Pasi Virtanen
  • Mikko Tenho
  • Päivi Mäki-Arvela
  • Jyri-Pekka Mikkola
Original Paper

Abstract

In this work, ionic liquid (IL) modified H-Beta zeolites were prepared and the physicochemical properties of the catalysts were investigated. IL modified zeolites were applied in 5-hydroxymethylfurfural (HMF) etherification to tert-butoxymethylfurfural (tBMF) which is a potential (bio)diesel component. The best catalyst, IL-H-Beta-25, yielded at BMF selectivity of 76 % corresponding to a HMF conversion of 46 %.

Keywords

Etherification HMF Ionic liquids SILCA 

Notes

Acknowledgments

This work is part of the activities at the Åbo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Program (2000–2011) appointed by the Academy of Finland. The Academy of Finland is gratefully acknowledged for financial support. In Sweden, the Bio4Energy Programme and Kempe Foundations are acknowledged. The Cost action CM0903 (UbioChem) is also acknowledged.

References

  1. 1.
    Alonso DM, Bond JQ, Dumesic JA (2010) Green Chem 12:1493CrossRefGoogle Scholar
  2. 2.
    Mäki-Arvela P, Salminen E, Riittonen T, Virtanen P, Kumar N, Mikkola J-P (2012) Int J Chem Eng 2012:1–10CrossRefGoogle Scholar
  3. 3.
    Gruter GJM (2012) US Patent, US20100218416A1Google Scholar
  4. 4.
    Mun J, Sim H (2012) Handbook of ionic liquids. Nova Science Publishers Inc., New YorkGoogle Scholar
  5. 5.
    Bonhote P, Dias A, Papageorgiou N, Kalyanasundaram K, Gräzel M (1996) Inorg Chem 35:1168CrossRefGoogle Scholar
  6. 6.
    Sheldon R (2001) Chem Commun 2399Google Scholar
  7. 7.
    Gordon CM (2001) Appl Catal 222:201Google Scholar
  8. 8.
    Mikkola J-P, Virtanen P, Karhu H, Salmi T, Murzin DY (2006) Green Chem 8:197CrossRefGoogle Scholar
  9. 9.
    Mehnert CP, Mozeleski EJ, Cook RA (2002) Chem Commun 3010Google Scholar
  10. 10.
    Hara P, Mikkola J-P, Murzin DY, Kanerva LT (2010) J Mol Catal B 67:129CrossRefGoogle Scholar
  11. 11.
    Virtanen P, Karhu H, Kordas K, Mikkola J-P (2007) Chem Eng Sci 62:3660CrossRefGoogle Scholar
  12. 12.
    Valkenberg MH, deCastro C, Hölderich WF (2002) Green Chem 4:88CrossRefGoogle Scholar
  13. 13.
    Shi F, Zhang Q, Li D, Deng Y (2005) Chem Eur J 11:5279CrossRefGoogle Scholar
  14. 14.
    Kim DW, Chi DY (2004) Angew Chem Int Ed 43:483CrossRefGoogle Scholar
  15. 15.
    Mallick B (2009) Ionische Flüssigkeiten auf Basis von komplexen Übergangsmetallhalogeniden. PhD Thesis, University of CologneGoogle Scholar
  16. 16.
    Lanzafame P, Temi D, Perathoner S, Centi G, Macario A, Aloise A, Giordano G (2011) Catal Today 175:435CrossRefGoogle Scholar
  17. 17.
    Kim J, Kim D, Han J, Kang M, Kim JM, Yie J (2003) Catal Today 87:195CrossRefGoogle Scholar
  18. 18.
    Coker E, Roelofsen D, Barrer R, Jansen J, Bekkum H (1998) Microporous Mesoporous Mater 22:261CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • Eero Salminen
    • 1
  • Narendra Kumar
    • 1
  • Pasi Virtanen
    • 1
  • Mikko Tenho
    • 2
  • Päivi Mäki-Arvela
    • 1
  • Jyri-Pekka Mikkola
    • 1
    • 3
  1. 1.Laboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry CentreÅbo Akademi UniversityÅbo-TurkuFinland
  2. 2.Laboratory of Industrial Physics, Department of PhysicsTurku UniversityTurkuFinland
  3. 3.Technical Chemistry, Department of Chemistry, Chemical-Biological CentreUmeå UniversityUmeåSweden

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