Topics in Catalysis

, Volume 55, Issue 7–10, pp 565–570 | Cite as

Rh(III) Pyridinium Substituted Bipyridine Complexes as Catalysts for Arene H/D Exchange

  • J. Brannon Gary
  • Tyler J. Carter
  • Melanie S. Sanford
Original Paper

Abstract

This report describes the synthesis of Rh(III) complexes containing a pyridinium-substituted bipyridine ligand. The catalytic activity of these complexes in H/D exchange reactions between arenes and acetic acid-d4 has been evaluated.

Keywords

C−H activation H/D exchange Rhodium Bipyridine 

Notes

Acknowledgments

We thank the NSF for support of this work through the Center for Enabling New Technologies through Catalysis (CENTC). In addition, JBG gratefully acknowledges the National Science Foundation (Graduate Research Fellowship) and Rackham Graduate School (Murrill Memorial Scholarship) for financial support.

Supplementary material

11244_2012_9825_MOESM1_ESM.docx (1.6 mb)
Supplementary material 1 (DOCX 1662 kb)

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Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • J. Brannon Gary
    • 1
  • Tyler J. Carter
    • 1
  • Melanie S. Sanford
    • 1
  1. 1.Department of ChemistryUniversity of MichiganAnn ArborUSA

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