Topics in Catalysis

, Volume 55, Issue 1–2, pp 84–92

Chemisorption and Dehydration of Ethanol on Silica: Effect of Temperature on Selectivity

Original Paper

DOI: 10.1007/s11244-012-9771-9

Cite this article as:
Luts, T. & Katz, A. Top Catal (2012) 55: 84. doi:10.1007/s11244-012-9771-9

Abstract

Dissociative chemisorption of ethanol on partially dehydroxylated silica is investigated by (i) exposing silica to gas-phase ethanol at various temperatures (ranging between 373 and 773 K) and (ii) analyzing the material using temperature-programmed desorption and in situ infrared spectroscopy. This chemisorption leads to formation of isolated surface ethoxide species via dehydration of ethanol at reaction temperatures above 573 K, and, at lower temperatures, it favors the synthesis of silanol–ethoxide functionality via a pathway involving opening of siloxane Si–O–Si bridges. The activation barrier for ethene desorption from the isolated surface ethoxide species is considerably higher relative to that for ethanol desorption from the hydrogen-bound silanol–ethoxide pairs. These single-turnover experiments allow predicting the product distribution of ethanol chemisorption on silica depending on the treatment conditions, e.g. temperature of interaction between ethanol and silica, and suggest why, in general, dehydration catalysis on silica requires high temperatures, in order to avoid non-productive chemisorption via opening of siloxane bridges.

Keywords

Chemisorption Silica Ethanol Ethene TPD Dehydration Infrared spectroscopy 

Supplementary material

11244_2012_9771_MOESM1_ESM.doc (404 kb)
Supplementary material 1 (DOC 404 kb)

Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  1. 1.Department of Chemical and Biomolecular EngineeringUniversity of California at BerkeleyBerkeleyUSA

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