Topics in Catalysis

, Volume 48, Issue 1–4, pp 153–157 | Cite as

Catalyst Compartmentalization in Dynamic Kinetic Resolutions

  • A. F. Fois
  • A. Yap
  • A. F. Masters
  • Th. Maschmeyer
Original Paper

Abstract

Catalytic nanoreactors, prepared by encapsulation of Zeolite H-Beta using a Layer-by-Layer (LbL) assembly of polyelectrolytes, have been examined in the Dynamic Kinetic Resolution (DKR) of secondary alcohols. The encapsulation of the acidic zeolite racemisation catalyst protects the pH-sensitive enzyme. This approach represents a convenient method of catalyst protection in multi-catalyst systems.

Keywords

Nanoreactors Compartmentalization Cascade reaction Catalyst Dynamic Kinetic Resolution 

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • A. F. Fois
    • 1
  • A. Yap
    • 1
  • A. F. Masters
    • 1
  • Th. Maschmeyer
    • 1
  1. 1.Laboratory of Advanced Catalysis for Sustainability, School of ChemistryThe University of SydneySydneyAustralia

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