Topics in Catalysis

, Volume 46, Issue 3–4, pp 402–413 | Cite as

Tunability of Propane Conversion over Alumina Supported Pt and Rh Catalysts

  • William C. Chueh
  • Zongping Shao
  • Sossina M. Haile
Original Paper


Propane conversion over alumina supported Pt and Rh (1 wt% metals loading) was examined under fuel rich conditions (C3H8:O2:He = 1:2.25:9) over the temperature range 450–650 °C. Morphological characteristics of the catalyst materials were varied by calcining at selected temperatures between 500 and 1,200 °C. X-ray diffraction and BET analysis showed the treatment generated catalyts metals with particle sizes in the range of <10 to >500 nm, and support surface areas in the range of 20–240 m2/g. Remarkably, both Rh and Pt yielded product compositions close to equilibrium values (with high H2 and CO selectivity, complete oxygen conversion and almost complete propane conversion) so long as the metal particle size was sufficiently low, ≲10–15 nm. In cases where the particle size was large, primarily complete oxidation rather than partial oxidation products were observed, along with unreacted C3H8, indicative of a direct oxidation pathway in which gas-phase CO and H2 are not present as intermediate species. It is proposed that the high resistance of Rh to coarsening is largely responsible for the observation of a higher selectivity of this material for syngas products when prepared by procedures similar to those for Pt. Overall, the tunability of the product composition obtained over Rh and Pt via processing steps has direct significance for the incorporation of such catalyts into the anodes of solid oxide fuel cells.


Pt/Al2O3 Rh/Al2O3 Propane partial oxidation Mental particle coarsening SOFC anode catalyst 



The authors gratefully acknowledge the assistance of Carol Garland (Caltech) in obtaining the TEM images and Dr. David G. Goodwin (Caltech) for insightful discussions. This study was funded by DARPA, Microsystems Technology Office and by ONR, Office of Electrochemical Power Science and Technology. Additional support was provided by the National Science Foundation (DMR-0080065) via Caltech’s Center for the Science and Engineering of Materials, an NSF Materials Research Science and Engineering Center (MRSEC).


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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • William C. Chueh
    • 1
  • Zongping Shao
    • 1
    • 2
  • Sossina M. Haile
    • 1
  1. 1.Materials ScienceCalifornia Institute of TechnologyPasadenaUSA
  2. 2.College of Chemistry and Chemical EngineeringNanjing University of TechnologyNanjingP.R. China

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