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Enamines of 1,3-dimethylbarbiturates and their symmetrical palladium(II) complexes: synthesis, characterization and biological activity

  • Rukiye FırıncıEmail author
  • Erkan Fırıncı
  • Gamze Başbülbül
  • Mustafa Berk Dabanca
  • Duygu Barut Celepci
  • M. Emin Günay
Article
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Abstract

Three 1,3-dimethylbarbiturate-enamine derivatives and their symmetrical palladium(II) complexes were prepared and characterized by spectroscopic methods. In addition, the structures of the complexes were determined by single-crystal X-ray diffraction. The X-ray diffraction studies revealed the geometry around the Pd(II) atom in each complex is almost perfectly square-planar. Also, the ligands and their palladium(II) complexes were tested for antifungal and antibacterial activity against various clinical and food-borne microorganisms, revealing promising biological activities.

Notes

Acknowledgements

This work was funded by “Scientific Research Project Unit (BAP) of Adnan Menderes University” (Project No: FEF-17020). Also, the authors thank the X-ray Laboratory, Faculty of Science, Dokuz Eylül University, for use of Oxford-Rigaku Xcalibur Eos diffractometer (purchased under University Research grant No: 2010. KB.FEN.13).

Supplementary material

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Supplementary material 1 (DOCX 1118 kb)

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Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of Arts and SciencesAydın Adnan Menderes UniversityEfeler, AydınTurkey
  2. 2.Department of Biology, Faculty of Arts and SciencesAydın Adnan Menderes UniversityEfeler, AydınTurkey
  3. 3.Department of Physics, Faculty of ScienceDokuz Eylül UniversityBuca, IzmirTurkey

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