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Transition Metal Chemistry

, Volume 44, Issue 2, pp 115–123 | Cite as

Hydrogen-bonded and π-stacked nickel(II) thiosemicarbazone complexes: Synthesis, spectral and structural studies

  • Şükriye Güveli
  • Namık Özdemir
  • Tülay Bal-DemirciEmail author
  • Mustafa Serkan Soylu
  • Bahri Ülküseven
Article
  • 169 Downloads

Abstract

Mixed ligand Ni(II) complexes were synthesized from triphenylphosphine and S-methyl- or S-ethyl-isothiosemicarbazone ligands derived from 3-bromo-5-chloro-2-hydroxy-benzaldehyde. The complexes were characterized by physicochemical and spectroscopic methods. In addition, their molecular structures were determined by single-crystal X-ray diffraction. In both complexes, the Ni atom has a near square-planar geometry, being coordinated by the phenolato oxygen, azomethine nitrogen and amine nitrogen atoms of the thiosemicarbazone ligands, together with the phosphorus atom of the triphenylphosphine. The S-methyl complex includes an additional free thiosemicarbazone ligand in the asymmetric unit. X-ray analysis shows that O–H···N, N–H···N, C–H···N and C–H···O-type hydrogen bonds and ππ stacking interactions are responsible for stabilizing the crystal structures.

Notes

Acknowledgements

This work was supported by the Scientific Research Projects Coordination Unit of İstanbul University (Project Number: BYP-2017-21222).

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Copyright information

© Springer Nature Switzerland AG 2018

Authors and Affiliations

  • Şükriye Güveli
    • 1
  • Namık Özdemir
    • 2
  • Tülay Bal-Demirci
    • 1
    Email author
  • Mustafa Serkan Soylu
    • 3
  • Bahri Ülküseven
    • 1
  1. 1.Department of Chemistry, Engineering FacultyIstanbul University-CerrahpaşaAvcılar, IstanbulTurkey
  2. 2.Department of Mathematics and Science Education, Faculty of EducationOndokuz Mayıs UniversitySamsunTurkey
  3. 3.Department of Physics, Faculty of Arts and SciencesGiresun UniversityGiresunTurkey

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