Advertisement

Transition Metal Chemistry

, Volume 44, Issue 2, pp 107–114 | Cite as

Structures and photocatalytic performance of two d10 metal-based coordination polymers containing mixed building units

  • Lu LuEmail author
  • Jun Wang
  • Feng Chen
  • Lin-Tao Wei
  • Li-Min Lin
  • Bao-Hong LiEmail author
  • Amita Singh
  • Abhinav KumarEmail author
Article
  • 111 Downloads

Abstract

The linker 1,4-bis(2-methyl-imidazole-yl)-butane (bib) was used to construct two coordination polymers, specifically [Cd(bib)(ipa)]n (1) and [Zn(bib)(tpa)]n (2), in the presence of isophthalic acid (H2ipa) and terephthalic acid (H2tpa), respectively, under solvothermal conditions. Topological analyses reveal that the crystal of complex 1 consists of a 3D threefold interpenetrating network with Schläfli symbol {65.8}, while complex 2 possesses a 2D wavelike layer structure with Schläfli symbol {66}. The photocatalytic properties of both complexes for the degradation of methyl violet have been explored, revealing that complex 2 is a better photocatalyst than 1. A mechanism for the photocatalytic properties of the complexes is proposed, based on the results of density of states (DOS) and partial DOS calculations.

Notes

Acknowledgements

The authors acknowledge financial assistance from Sichuan University of Science and Engineering (Nos. 2015RC26, 2015RC29 and 2017RCL02), the Education Committee of Sichuan Province (Nos. 17ZA0264, 17ZB0312, 18ZB0422, 18ZB0425), the Project of Zigong Science and Technology (No. 2016HG06), the Opening Project of Key Laboratory of Green Catalysis of Sichuan Institutes of High Education (No. LYJ1705) and Innovative Entrepreneurial Training Plan of undergraduates in Guangdong Province (Nos. 201810571008, 201810571012, 201810571047, 201810571082, 201810571061, 201810571091).

Supplementary material

11243_2018_274_MOESM1_ESM.docx (219 kb)
Supplementary material 1 (DOCX 218 kb)

References

  1. 1.
    Yoon MY, Srirambalaji R, Kim K (2012) Chem Rev 112:1196CrossRefGoogle Scholar
  2. 2.
    Chen CC, Ma WH, Zhao JC (2010) Chem Soc Rev 39:4206CrossRefGoogle Scholar
  3. 3.
    Wen T, Zhang DX, Zhang J (2013) Inorg Chem 52:12CrossRefGoogle Scholar
  4. 4.
    Wang XL, Han N, Lin HY, Tian AX, Liu GC, Zhang JW (2014) Dalton Trans 43:2052CrossRefGoogle Scholar
  5. 5.
    Zhang LN, Lu ST, Zhang C, Du CX, Hou HW (2015) CrystEngComm 17:846CrossRefGoogle Scholar
  6. 6.
    Wang FQ, Wang CM, Yu JC, Xu KH, Li XY, Fu YY (2016) Polyhedron 105:49CrossRefGoogle Scholar
  7. 7.
    Mu B, Li CX, Song M, Ren YL, Huang RD (2016) CrystEngComm 18:3086CrossRefGoogle Scholar
  8. 8.
    Liao ZL, Li GD, Bi MH, Chen JS (2008) Inorg Chem 47:11CrossRefGoogle Scholar
  9. 9.
    Guo J, Yang J, Liu YY, Ma JF (2012) CrystEngComm 14:6609CrossRefGoogle Scholar
  10. 10.
    Li HX, Zhang XY, Huo YN, Zhu J (2007) Environ Sci Technol 41:4410CrossRefGoogle Scholar
  11. 11.
    Wang SB, Wang XC (2015) Small 11:3097CrossRefGoogle Scholar
  12. 12.
    Gao YW, Li SM, Li YX, Yao LY, Zhang H (2017) Appl Catal B Environ 202:165CrossRefGoogle Scholar
  13. 13.
    Silva CG, Corma A, García A (2010) J Mater Chem 20:3141CrossRefGoogle Scholar
  14. 14.
    So MC, Wiederrecht GP, Mondloch JE, Huppand JT, Farha OK (2015) Chem Commun 51:3501CrossRefGoogle Scholar
  15. 15.
    Liu J, Wu J, Li F, Liu W, Li B, Wang J, Li Q, Yadav R, Kumar A (2016) RSC Adv 6:31161CrossRefGoogle Scholar
  16. 16.
    Jin JC, Wu XR, Luo ZD, Deng FY, Liu JQ, Singh A, Kumar A (2017) CrystEngComm 19:4368CrossRefGoogle Scholar
  17. 17.
    Wang J, Wu X, Liu J, Li B, Singh A, Kumar A, Batten SR (2017) CrystEngComm 19:3519CrossRefGoogle Scholar
  18. 18.
    Lu L, Wang J, Xie B, Liu J, Yadav R, Singh A, Kumar A (2017) New J Chem 41:3537CrossRefGoogle Scholar
  19. 19.
    Wang J, Bai C, Hu HM, Yuan F, Xue GL (2017) J Solid State Chem 249:87CrossRefGoogle Scholar
  20. 20.
    Sheldrick GM (2015) Acta Crystallogr Sect A Found Adv 71:3CrossRefGoogle Scholar
  21. 21.
    Becke AD (1993) J Chem Phys 98:5648CrossRefGoogle Scholar
  22. 22.
    Lee CT, Yang WT, Parr RG (1998) Phys Rev B Condens Matter Mater Phys 37:785CrossRefGoogle Scholar
  23. 23.
    Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Montgomery JA, Vreven JT, Kudin KN, Burant JC, Millam JM, Iyengar SS, Tomasi, J, Barone V, Mennucci B, Cossi M, Scalmani G, Rega N, Petersson GA, Nakatsuji H, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Klene M, Li X, Knox JE, Hratchian HP, Cross JB, Bakken V, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski J W, Ayala PY, Morokuma K, Voth GA, Salvador P, Dannenberg JJ, Zakrzewski VG, Dapprich S, Daniels AD, Strain MC, Farkas O, Malick DK, Rabuck AD, Raghavachari K, Foresman JB, Ortiz JV, Cui Q, Baboul AG, Clifford S, Cioslowski J, Stefanov BB, Liu G, Liashenko A, Piskorz P, Komaromi I, Martin RL,Fox DJ, Keith T, Al-Laham MA, Peng CY, Nanayakkara A, Challacombe M, Gill PMW, Johnson B, Chen W, Wong WM, Gonzalez C, Pople JA (2009) Gaussian 09 revision B.01, Gaussian, Inc., WallingFord CTGoogle Scholar
  24. 24.
    O’Boyle NM, Tenderholt AL, Langner KM (2008) J Comput Chem 29:839CrossRefGoogle Scholar
  25. 25.
    Zhou HF, He T, Yue KF, Liu YL, Zhou CS, Yan N, Wang Y (2016) Cryst Growth Des 16:3961CrossRefGoogle Scholar
  26. 26.
    Hu JM, Guo R, Liu YG, Cui GH (2016) Inorg Chim Acta 450:418CrossRefGoogle Scholar
  27. 27.
    Mitkina TV, Zakharchuk NF, Naumov DY, Gerasko OA, Fenske D, Fedin VP (2008) Inorg Chem 47:6748CrossRefGoogle Scholar
  28. 28.
    Britten J, Hearns NGR, Preuss KE, Richardson JF, Bin-Salamon S (2007) Inorg Chem 46:3934CrossRefGoogle Scholar
  29. 29.
    Meng JX, Lu Y, Li YG, Fu H, Wang EB (2011) CrystEngComm 13:2479CrossRefGoogle Scholar
  30. 30.
    Guo J, Yang J, Liu YY, Ma JF (2012) CrystEngComm 14:6609CrossRefGoogle Scholar
  31. 31.
    Mahata P, Madras G, Natarajan S (2006) J Phys Chem B 110:13759CrossRefGoogle Scholar
  32. 32.
    Gong Y, Li J, Qin J, Wu T, Cao R, Li J (2011) Cryst Growth Des 11:1662CrossRefGoogle Scholar
  33. 33.
    Wang CM, Wang FQ, Dong CF, Yu ZC, Wang ZC, Zhao YN, Li GD (2015) Z Anorg Allg Chem 641:1125CrossRefGoogle Scholar
  34. 34.
    Wang FQ, Dong CF, Wang ZC, Cui YR, Wang CM, Zhao YN, Li GD (2014) Eur J Inorg Chem 36:6239CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2018

Authors and Affiliations

  1. 1.School of Chemistry and Environmental EngineeringSichuan University of Science and EngineeringZigongPeople’s Republic of China
  2. 2.Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of PharmacyGuangdong Medical UniversityDongguanPeople’s Republic of China
  3. 3.Department of Chemistry, Faculty of ScienceUniversity of LucknowLucknowIndia

Personalised recommendations