Transition Metal Chemistry

, Volume 41, Issue 7, pp 775–781 | Cite as

Synthesis of a palladium(II) complex of a N-heterocylic carbene via transmetalation: crystal structure and antibacterial studies

  • Rosenani A. Haque
  • Umie F. M. Haziz
  • A. A. Amirul
  • Noor Shaheeda
  • Mohd R. Razali
Article

Abstract

An Ag(I)-N-heterocylic carbene (NHC) complex, [Ag(L)2]PF6 (L = 1-(2′-methylbenzyl)-3-(2″-propyl)benzimidazolium), was used as a transfer agent for the synthesis of a Pd(II)–NHC complex, formulated as [PdCl(L)2(MeCN)]PF6 (Pd1). The complex Pd1 was characterized by 1H and 13C NMR, FTIR spectroscopy and elemental analysis. Single crystal X-ray diffraction analysis reveals that the Pd(II) atom has a square planar geometry. This complex was screened for its antibacterial potential against the Gram-negative bacteria Escherichia coli (ATCC 25922) and the Gram-positive bacteria Staphylococcus aureus (ATCC 12600). These results are compared with those obtained for a standard antibiotic, ampicillin, and also the corresponding Ag(I)–NHC complex.

Supplementary material

11243_2016_78_MOESM1_ESM.doc (1.5 mb)
Supplementary material 1 (DOC 1559 kb)

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Copyright information

© Springer International Publishing Switzerland 2016

Authors and Affiliations

  • Rosenani A. Haque
    • 1
  • Umie F. M. Haziz
    • 1
  • A. A. Amirul
    • 2
    • 3
  • Noor Shaheeda
    • 2
  • Mohd R. Razali
    • 1
  1. 1.School of Chemical SciencesUniversiti Sains Malaysia (USM)GelugorMalaysia
  2. 2.School of Biological SciencesUniversiti Sains Malaysia (USM)GelugorMalaysia
  3. 3.Centre of Chemical BiologyUniversiti Sains MalaysiaGelugorMalaysia

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