Transition Metal Chemistry

, Volume 41, Issue 4, pp 365–373 | Cite as

Syntheses, characterization, and magnetic properties of two 3D frl topological frameworks constructed from nickel diphosphonates

  • Qing-Jun Niu
  • Yue-Qing Zheng
  • Hong-Lin Zhu
  • Wei Xu
Article
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Abstract

Two 3D open-framework nickel diphosphonates, [Ni3(H2zdn)2(bpe)2]·4H2O (1) and [Ni3(H2zdn)2(bpy)2]·bpy·4H2O (2) (H5zdn = zoledronic acid, bpe = trans-4,4-vinylenedipyridine, bpy = 4,4′-dipyridyl), have been prepared and structurally characterized. In complex 1, the metal centers are linked by zoledronate ligands to generate a 2D layer, containing 14- and 24-membered rings. These 2D layers are further pillared by the bpe ligands into a 3D network structure with cylindrical channels. Magnetic susceptibility measurements reveal ferrimagnetism at T c = 3.8 and 4.4 K for complexes 1 and 2, respectively.

Keywords

Graphene Oxide Zoledronic Acid Graphite Oxide Antiferromagnetic Interaction Lattice Water Molecule 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Notes

Acknowledgments

This project was sponsored by K. C. Wong Magna Fund in Ningbo University and supported by the Scientific Research Fund of Zhejiang Provincial Education Department. The authors thank xi2004 for the refinement of crystal structure data.

Supplementary material

11243_2016_30_MOESM1_ESM.doc (2.4 mb)
Supplementary material 1 (DOC 2489 kb)

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Copyright information

© Springer International Publishing Switzerland 2016

Authors and Affiliations

  • Qing-Jun Niu
    • 1
  • Yue-Qing Zheng
    • 1
  • Hong-Lin Zhu
    • 1
  • Wei Xu
    • 1
  1. 1.Crystal Engineering Division, Center of Applied Solid State Chemistry ResearchNingbo UniversityNingboPeople’s Republic of China

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