Transition Metal Chemistry

, Volume 38, Issue 8, pp 849–853 | Cite as

Synthesis, structure and thermogravimetric analysis of Ni–Cd and Cu–Cd heterometallic complexes based on flexible carboxylate ligands

  • Yang Liu
  • Dai-Zhi Kuang
  • Yong-Lan Feng
  • Wei-Wei Fu
Article
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Accepted:

Abstract

Two 3d–4d heterometallic coordination polymers, namely NiCd(mal)2(H2O)4 (1) and [CuCd(bicH2)(NO3)Cl2(H2O)]⋅H2O (2) [H2mal = malonic acid, bicH3 = N,N-bis(2-hydroxyethyl) glycine], have been synthesized under mild conditions and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectrophotometry. Complex 1 is a Ni–Cd heterometallic polymer with 2D extended structure bridged by the mal2− groups. Complex 2 displays an intriguing 3D Cu–Cd architecture and is the first 3d–4d heterometallic bicinate complex. The TG analyses of both complexes are reported.

Keywords

Malonic Acid Nitrate Anion Bicine Carboxylate Oxygen Atom Lattice Water Molecule 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Notes

Acknowledgments

This work was supported by the Open Research Fund of the Key Laboratory in Hunan Province (Grant No. 10K01 and Grant No. 13K105) and Science and Technology Project of Hengyang (Grant No. 2012KJ29).

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Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  • Yang Liu
    • 1
  • Dai-Zhi Kuang
    • 1
  • Yong-Lan Feng
    • 1
  • Wei-Wei Fu
    • 1
  1. 1.Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials ScienceHengyang Normal UniversityHengyangPeople’s Republic of China

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