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Synthesis and structural characterization of some titanium butoxides modified with chloroacetic acids

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Abstract

Reactions of Ti(OBus)4 and Ti(OBun)4 with chloroacetic acids (mono-, di-, and tri-) were carried out in toluene in 1:1 and 1:2 molar ratios at room temperature to generate new precursors of titania. These modified alkoxides/oxo-alkoxides were characterized by spectroscopic methods. A solution of Ti(OBun)2(OOCCCl3)2 in toluene left for crystallization at −30 °C yielded single crystals of the product Ti62-O)23-O)22-OC4H9)2(OC4H9)6(OOCCCl3)8. Single-crystal X-ray diffraction revealed the molecular structure to be composed of a hexanuclear unit in which two Ti2O10 units (made by two edge-sharing octahedra) are linked with two corner-sharing octahedra.

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Acknowledgments

The authors are grateful to the Department of Science and Technology (DST) project Grant SR/ME/S-3/0016/2008. One of the authors is also grateful to the University Grants Commission–Maulana Azad National Fellowship (UGC-MANF).

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Correspondence to Ashutosh Pandey.

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Ambreen, S., Gupta, K., Singh, S. et al. Synthesis and structural characterization of some titanium butoxides modified with chloroacetic acids. Transition Met Chem 38, 835–841 (2013). https://doi.org/10.1007/s11243-013-9756-y

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Keywords

  • Alkoxide
  • Titanium Atom
  • Chloroacetic Acid
  • Bridge Oxygen Atom
  • Titanium Alkoxide