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Nickel(II) and zinc(II) complexes of a pyridine ligand bearing a tetrathiafulvalene substituent

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Abstract

The synthesis, crystal structures, and electrochemical properties of the coordination complexes, NiBr2(ept)2 and ZnBr2(ept)2 (ept = 4,5-ethylenedioxy-3′-(3′-pyridyl)-tetrathiafulvalene) are reported. Both complexes are mononuclear, with monodentate coordination of the ept ligand through the pyridine nitrogen. Cyclic voltammetry measurements for both complexes show a sizable interaction involving the electroactive ept ligand, with stabilization of the oxidized forms of the complexes.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (20902051), Ningbo Natural Science Foundation (2010A610186), Ningbo Science and Technology Innovation Team (2011B2002), Foundation of the Education Committee of Zhejiang Province (Y201120345), and SRF for ROCS, SEM.

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Correspondence to Xun-wen Xiao or Jian-ping Yang.

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Xiao, X., He, Y., Sun, L. et al. Nickel(II) and zinc(II) complexes of a pyridine ligand bearing a tetrathiafulvalene substituent. Transition Met Chem 37, 771–775 (2012). https://doi.org/10.1007/s11243-012-9650-z

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Keywords

  • Free Ligand
  • Cyclic Voltammetry Measurement
  • Tetrathiafulvalene
  • ZnBr2
  • NiBr2