Transition Metal Chemistry

, Volume 37, Issue 3, pp 257–263 | Cite as

Solvothermal synthesis and characterization of coordination polymers of cobalt(II) and zinc(II) with succinic acid

  • Selçuk Demir
  • Günay Kaya Kantar
  • Yıldıray Topcu
  • Qiaowei Li
Article
First Online:
Received:
Accepted:

Abstract

The complexes [Co(C4H4O4)]n (1) and [Zn(im)2(C4H4O4)]n (2) (C4H4O4 = succinate dianion, suc; im = imidazole) have been synthesized solvothermally and characterized by elemental analysis, IR, TG–DTA, and single-crystal X-ray diffraction techniques. Complex 1 is the first anhydrous member of the cobalt succinate family and has high thermal stability under a static air atmosphere, up to 425 °C, and complex 2 is a 1D coordination polymer. In addition, a new synthesis method and some properties of the known [Co(HCOO)2·2H2O]n (3) complex are reported. After in situ synthesis of 3 via decomposition of DMF at 140 °C, it was found that complex 3 can adsorb some solvents repeatedly and is selective for H2O.

Keywords

Co3O4 Coordination Polymer PXRD Pattern CoSO4 Calculated Mass Loss 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in to check access.

Notes

Acknowledgments

This work was financially supported by Rize University (No. 2010.102.02.2). S. Demir thanks the Council of Higher Education (YÖK), TURKEY, for a postdoctoral fellowship, Prof. Omar M. Yaghi from Center for Reticular Chemistry, University of California, Los Angeles, for the opportunity to study in his lab and using crystallographic equipment, and Assoc. Prof. Dr. Ertan Şahin from Atatürk University for crystallographic data collection of 2.

References

  1. 1.
    Robin AY, Fromm KM (2006) Coord Chem Rev 250:2127–2157CrossRefGoogle Scholar
  2. 2.
    Rao CNR, Cheetham AK, Thirumurugan A (2008) J Phys Condens Matter 20:083202CrossRefGoogle Scholar
  3. 3.
    Rowsell JLC, Yaghi OM (2004) Microporous Mesoporous Mater 73:3–14CrossRefGoogle Scholar
  4. 4.
    Eddaoudi M, Moler D, Li H, Reineke TM, O’Keeffe M, Yaghi OM (2001) Acc Chem Res 34:319–330CrossRefGoogle Scholar
  5. 5.
    Long JR, Yaghi OM (2009) Chem Soc Rev 38:1213–1214CrossRefGoogle Scholar
  6. 6.
    Kuppler RJ, Timmons DJ, Fang Q-R, Li J-R, Makal TA, Young MD, Yuan D, Zhao D, Zhuang W, Zhoua H-C (2009) Coord Chem Rev 253:3042–3066CrossRefGoogle Scholar
  7. 7.
    Kurmoo M (2009) Chem Soc Rev 38:1353–1379CrossRefGoogle Scholar
  8. 8.
    Czaja AU, Trukhan N, Müller U (2009) Chem Soc Rev 38:1284–1293CrossRefGoogle Scholar
  9. 9.
    Allendorf MD, Bauer CA, Bhakta RK, Houk RJT (2009) Chem Soc Rev 38:1330–1352CrossRefGoogle Scholar
  10. 10.
    Murray LJ, Dinca M, Long JR (2009) Chem Soc Rev 38:1294–1314CrossRefGoogle Scholar
  11. 11.
    Guillou N, Livage C, Férey G (2006) Eur J Inorg Chem 24:4963–4978CrossRefGoogle Scholar
  12. 12.
    Forster PM, Stock N, Cheetham AK (2005) Angew Chem Int Ed 44:7608–7611CrossRefGoogle Scholar
  13. 13.
    Long L-S, Chen X-M, Tong M-L, Sun Z-G, Ren Y-P, Huang R-B, Zheng L-S (2001) J Chem Soc Dalton Trans 19:2888–2890CrossRefGoogle Scholar
  14. 14.
    Zheng Y-Q, Lin J-L (2001) Z Kristallogr New Cryst Struct 216:139–140Google Scholar
  15. 15.
    Rigaku (2005) CrystalClear, Rigaku Corporation, Tokyo, JapanGoogle Scholar
  16. 16.
    Altomare A, Burla MC, Camalli M, Cascarano GL, Giacovazzo C, Guagliardi A, Moliterni AGG, Polidori G, Spagna R, SIR97: (1999) J Appl Cryst 32:115Google Scholar
  17. 17.
    Sheldrick GM (2008) Acta Crystallogr A64:112–122Google Scholar
  18. 18.
    Farrugia LJ (1999) J Appl Cryst 32:837CrossRefGoogle Scholar
  19. 19.
    McArdle P, Gilligan K, Cunningham D, Dark R, Mahon M (2004) CrystEngCommun 6:303–309CrossRefGoogle Scholar
  20. 20.
    Farrugia LJ (1997) J Appl Cryst 30:565CrossRefGoogle Scholar
  21. 21.
    Kaufman A, Afshar C, Rossi M, Zacharias DE, Glusker JP (1993) Struct Chem 4:191–198CrossRefGoogle Scholar
  22. 22.
    Antsyshkina AS, Guseinova MK, Porai-Koshits MA (1967) Zhurnal Steakturnoi Khimii 8(2):365Google Scholar
  23. 23.
    Zelenak V, Vargova Z, Györyova K (2007) Spectrochim Acta Part A 66:262–272CrossRefGoogle Scholar
  24. 24.
    Demir S, Kaya G (2011) Z Anorg Allg Chem 637:456–461CrossRefGoogle Scholar
  25. 25.
    Demir S, Yilmaz VT, Yilmaz F, Buyukgungor O (2009) J Inorg Organomet Polym 19:342–347CrossRefGoogle Scholar
  26. 26.
    Bowden TA, Milton HL, Slawin AMZ, Lightfoot P (2003) Dalton Trans 5:936–939CrossRefGoogle Scholar
  27. 27.
    Zhang J, Kang Y, Zhang R-B, Li Z-J, Cheng J-K, Yao Y-G (2005) CrystEngCommun 7(28):177–178CrossRefGoogle Scholar
  28. 28.
    Musie GT, Li X, Powell DR (2004) Acta Cryst E60:m471–m472Google Scholar
  29. 29.
    Spek AL (2009) Acta Cryst D65:148–155Google Scholar
  30. 30.
    Arii T, Kishi A (1999) Thermochim Acta 325:157–165CrossRefGoogle Scholar
  31. 31.
    Kim DS, Forster PM, Toquin RL, Cheetham AK (2004) Chem Commun 2148–2149Google Scholar
  32. 32.
    Rossin A, Ienco A, Costantino F, Montini T, Credico BD, Caporali M, Gonsalvi L, Fornasiero P, Peruzzini M (2008) Cryst Growth Des 9:3302–3308CrossRefGoogle Scholar
  33. 33.
    Mallick A, Saha S, Pachfule P, Roy S, Banerjee R (2011) Inorg Chem 50:1392–1401CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2012

Authors and Affiliations

  • Selçuk Demir
    • 1
  • Günay Kaya Kantar
    • 1
  • Yıldıray Topcu
    • 2
  • Qiaowei Li
    • 3
  1. 1.Department of Chemistry, Faculty of Arts and SciencesRize UniversityRizeTurkey
  2. 2.Department of Chemical Engineering, Faculty of EngineeringOndokuz Mayis UniversitySamsunTurkey
  3. 3.Department of ChemistryFudan UniversityShanghaiPeople’s Republic of China

Personalised recommendations