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Hydrogen-bonded supramolecular structures constructed from trinuclear copper units

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Abstract

Four copper complexes with similar trinuclear copper units, [Cu6(Bmshp)2(SO4)2(H2O)7]·2H2O (1), [Cu3(Bmshp)(ClO4)2(H2O)4]·5H2O (2), [Cu3(Bmshp)(DMF)4(H2O)2]·H2O·2DMF·2ClO4 (3) and [Cu3(H2Bcshp)(ClO4)2(H2O)4]·3H2O (4) (H4Bmshp = 2,6-bis[(3-methoxysalicylidene)hydrazinocarbonyl]pyridine, H6Bcshp = 2,6-bis[(3-carboxylsalicylidene)hydrazinocarbonyl]pyridine), were synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction analysis. Due to the different anions, solvents and ligands used in the syntheses, complexes 14 exhibit diverse supramolecular structures constructed from the corresponding trinuclear copper units via H-bonds.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 20971029), Guangxi Natural Science Foundation (No. 2010GXNSFD013018 and 2010GXNSFF013001).

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Correspondence to Fu-Pei Liang.

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Qin, S., Huang, H., Chen, Z. et al. Hydrogen-bonded supramolecular structures constructed from trinuclear copper units. Transition Met Chem 36, 653 (2011). https://doi.org/10.1007/s11243-011-9515-x

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Keywords

  • Supramolecular Structure
  • Triclinic Space Group
  • OCH3 Group
  • Dark Green Crystal
  • Guest Water Molecule