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Synthesis and characterization of bis(O,O′-diisopropylmonothiophosphato)nickel(II) adducts and molecular structures of bis(pyridine)bis(O,O′-diisopropylmonothiophosphato)nickel(II) complex

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Abstract

The present work demonstrates the synthesis and characterization of adducts with bis(O,O′-diisopropylmonothiophosphato)nickel(II) complex, Ni{S(O)P(OiPr)2}2(L) n (n = 2, L = pyridine, 2-picoline, 3-picoline; n = 1, L = 2,2′-bipyridyl and 1,10-phenanthroline). The crystallographic investigation of Ni{S(O)P(OiPr)2}2(C5H5N)2 reveals distorted octahedral geometry around the central nickel(II) atom. The monothiophosphate moieties show anisobidentate coordination to the central metal, while the pyridine ligands are in cis positions. These nickel(II) adducts were characterized by elemental analysis, a range of spectroscopic techniques, and magnetic susceptibility measurement.

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References

  1. 1.

    Kabachnik MI, Joffe ST, Masterufukov TA (1955) Zh Obshch Khim 25:684

  2. 2.

    Kabachnik MI, Mastrukova TA, Shipov AE, Melentyeva TA (1960) Tetrahedron 9:10

  3. 3.

    Shrader G (1958) Chem Zentrabl 13:619

  4. 4.

    Aaron HS, Vyeda RT, Frack HF, Miller JI (1962) J Chem Soc 84:617

  5. 5.

    Arbusov BA, Jarmukhumetova DK, Nauk IA, SSR (1958) Otd Khim Nauk 1061

  6. 6.

    Takas NJ, Aitken JA (2007) J Solid State Chem 180:2034

  7. 7.

    Nasser FAK, Zuckerman JJ (1983) J Organomet Chem 244:17

  8. 8.

    Nasser FAK, Hossain MB, Vander Helm D, Zuckerman JJ (1983) Inorg Chem 22:3107

  9. 9.

    Issleib K, Walther B (1970) J Organomet Chem 22:375

  10. 10.

    Duncan IA (1978) Inorg Chim Acta 27:129

  11. 11.

    Avar G, Neumann WP (1977) J Organomet Chem 131:215

  12. 12.

    Glidwell C, Leslie EJ (1977) J Chem Soc Dalton Trans 527

  13. 13.

    Khaldy AAS (1999) Synth React Inorg Met Org Chem 29:643

  14. 14.

    Nagar PN (1988) Phosphorus Sulphur and Related Elem 40:177

  15. 15.

    Jain VK (1994) Coord Chem Rev 135:809

  16. 16.

    Garje SS, Jain VK (2003) Coord Chem Rev 236:35

  17. 17.

    Mokal VB, Jain VK, Tiekink ERT (1994) J Organomet Chem 471:53

  18. 18.

    Glidwell C (1977) Inorg Chim Acta 24:255

  19. 19.

    Bingham AL, Drake JE, Hursthouse MB, Light ME, Nirwan M, Ratnani R (2008) Polyhedron 27:1673

  20. 20.

    Panday JN (1986) Ph. D. Thesis, University of Rajasthan, Jaipur, pp 147

  21. 21.

    Jain VK (2001) J Indian Chem Soc 78:224

  22. 22.

    Poptani R (2007) Ph.D. Thesis, M. D. S. University, Ajmer, pp 74

  23. 23.

    Menzer S, Phillips JR, Salwin AMZ, Williams DJ, Woollins JD (2000) J Chem Soc Dalton Trans 32:69

  24. 24.

    Phillips JR, Poat JC, Salwin AMZ, Williams DJ, Wood PT, Woollins JD (1995) J Chem Soc Dalton Trans 23:69

  25. 25.

    Kuleczyeki A, Sarna S, Wachal A (1989) Tribologia 20:12

  26. 26.

    Metivier J (1956) Societe des Usines Chimiques Rhone-Poulenc, US 2752283

  27. 27.

    Wallace EG, Fancher LW (1958) Stauffer Chem Co, US 2854469

  28. 28.

    Bhasin CP, Drago GRS (1977) Physical methods in chemistry. W. B. Saunders, Philadelphia

  29. 29.

    Foss O (1947) Acta Chim Scand 1:8

  30. 30.

    Duisenberg AJM (1992) J Appl Crystallogr 25:92

  31. 31.

    Sheldrick GM (2003) SADABS V2.10, University of Gottingen, Germany

  32. 32.

    Sheldrick GM (1990) Acta Crystallogr 46:467

  33. 33.

    Farrugia LJ (1999) J Appl Crystallogr 32:837

  34. 34.

    Sheldrick GM (1997), SHELX, Structure Determination Software, University of Gottingen, Germany

  35. 35.

    Bingham AL, Drake JE, Light ME, Nirman M, Ratnani R (2006) Polyhedron 25:945

  36. 36.

    Holm RH, Everett GW, Horrocks WD (1966) J Am Chem Soc 88:1071

  37. 37.

    Dhingra MM, Govil G, Kanekar CR (1971) Chem Phys Lett 10:86

  38. 38.

    Zhang H, Fang L (2005) Acta Cryst E61:m180

  39. 39.

    You XZ, Xu Z, Yu YP, Liu SX, Lin CC (1986) Jieegou Huaxue 5:154

  40. 40.

    Sanchez G, Garcıa J, Meseguer DJ, Serrano JL, Perez J, Molins E, Lopez G (2004) Inorg Chim Acta 357:677

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Acknowledgments

S.B. is thankful for the generous financial support from the UGC, New Delhi. Authors are thankful to reviewers for their valuable suggestions.

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Correspondence to Subhash C. Bajia.

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Bajia, S.C., Mishra, A. & Butcher, R.J. Synthesis and characterization of bis(O,O′-diisopropylmonothiophosphato)nickel(II) adducts and molecular structures of bis(pyridine)bis(O,O′-diisopropylmonothiophosphato)nickel(II) complex. Transition Met Chem 36, 325–329 (2011). https://doi.org/10.1007/s11243-011-9474-2

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Keywords

  • Adduct
  • C5H5N
  • Bipyridyl
  • Lewis Base
  • Magnetic Susceptibility Measurement