Advertisement

Transition Metal Chemistry

, Volume 35, Issue 3, pp 373–379 | Cite as

Synthesis, spectroscopy and crystal structure determination of heteroleptic cobalt(II) silanethiolates with pyridine derivatives

  • Agnieszka PladzykEmail author
  • Katarzyna Baranowska
  • Patrycja Hapter
Article

Abstract

The synthesis and characterization of four new Co(II) tri-tert-butoxysilanethiolates with 3- and 4-methylpyridine are reported. Mononuclear complexes have been obtained in reactions with bimetallic [Co{μ-SSi(O t Bu)3}{SSi(O t Bu)3}(NH3)]2 as a Co(II) substrate. The new compounds have been characterized by single-crystal X-ray structure determination, UV–vis and FT-IR spectroscopy and elemental analysis. The complexes are tetra- and penta-coordinated with CoN2S2 and CoNO2S2 cores, respectively.

Keywords

Violet Crystal Pyridine Derivative tBuO Isotropic Temperature Factor Siloxy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    Vallee BL, Auld DS (1990) Biochemistry 29:5647–5659CrossRefGoogle Scholar
  2. 2.
    Berg JM (1989) Prog Inorg Chem 37:143CrossRefGoogle Scholar
  3. 3.
    Eklund H, Nordström B, Zeppezauer E, Söderlund G, Ohlsson I, Boiwe T, Söderberg BO, Tapia O, Brändén CI, Åkeson Å (1976) J Mol Biol 102:27–59CrossRefGoogle Scholar
  4. 4.
    Sytkowski AJ, Vallee BL (1979) Biochemistry 18:4095–4099CrossRefGoogle Scholar
  5. 5.
    Smith JN, Shirin Z, Carrano CJ (2003) J Am Chem Soc 125:868–869CrossRefGoogle Scholar
  6. 6.
    Lipton AS, Ellis PD (2007) J Am Chem Soc 129:9192–9200CrossRefGoogle Scholar
  7. 7.
    Anzellotti AI, Farrell NP (2008) Chem Soc Rev 37:1629–1651CrossRefGoogle Scholar
  8. 8.
    Vašák M, Kägi JHR (1981) Proc Natl Acad Sci USA 78:6709–6713 and references thereinCrossRefGoogle Scholar
  9. 9.
    Vašák M, Kägi JHR, Holmquist B, Vallee BL (1981) Biochemistry 20:6659–6664CrossRefGoogle Scholar
  10. 10.
    Corwin DT, Fikar R, Koch SA (1987) Inorg Chem 26:3079–3080CrossRefGoogle Scholar
  11. 11.
    Kimblin C, Bridgewater BM, Churchill DG, Hascall T, Parkin G (2000) Inorg Chem 39:4240–4243CrossRefGoogle Scholar
  12. 12.
    Rajagopalan PTR, Grimme S, Pei D (2000) Biochemistry 39:779–790CrossRefGoogle Scholar
  13. 13.
    Maret W (1989) Biochemistry 28:9944–9949CrossRefGoogle Scholar
  14. 14.
    Chang S, Karambelkar VV, Sommer RD, Rheingold AL, Goldberg AL (2002) Inorg Chem 41:239–248CrossRefGoogle Scholar
  15. 15.
    Piękoś R, Wojnowski W (1962) Z Anorg Allg Chem 318:212–216CrossRefGoogle Scholar
  16. 16.
    Becker B, Zalewska A, Konitz A, Wojnowski W (2001) Z Anorg Allg Chem 627:271–279CrossRefGoogle Scholar
  17. 17.
    Becker B, Zalewska A, Konitz A, Wojnowski W (2001) Polyhedron 30:2567–2576CrossRefGoogle Scholar
  18. 18.
    Becker B, Pladzyk A, Konitz A, Wojnowski W (2002) Appl Organometal Chem 16:517–524CrossRefGoogle Scholar
  19. 19.
    Kropidłowska A, Chojnacki J, Becker B (2007) Inorg Chim Acta 360:2363–2367CrossRefGoogle Scholar
  20. 20.
    Kloskowska M, Konitz A, Wojnowski W, Becker B (2006) Z Anorg Allg Chem 632:2424–2428CrossRefGoogle Scholar
  21. 21.
    Becker B, Dołęga A, Konitz A, Swinder L, Wojnowski W (2001) Z Anorg Allg Chem 627:280–286CrossRefGoogle Scholar
  22. 22.
    Becker B, Radacki K, Wojnowski W (1996) J Organomet Chem 521:39–49CrossRefGoogle Scholar
  23. 23.
    Dołęga A, Becker B, Chojnacki J, Konitz A, Wojnowski W (2004) Inorg Chim Acta 357:461–467CrossRefGoogle Scholar
  24. 24.
    Becker B, Dołęga A, Konitz A, Wojnowski W (2001) Polyhedron 20:949–956CrossRefGoogle Scholar
  25. 25.
    Pladzyk A, Baranowska K (2009) Z Anorg Allg Chem 635:1638–1644CrossRefGoogle Scholar
  26. 26.
    Dołęga A, Pladzyk A, Baranowska K, Jezierska J (2009) J Inorg Chim Acta 362:5085–5096CrossRefGoogle Scholar
  27. 27.
    Dołęga A, Baranowska K, Gudat D, Herman A, Stangret J, Konitz A, Śmiechowski M, Godlewska S (2009) Eur J Inorg Chem (24):3644–3660Google Scholar
  28. 28.
    Ciborska A, Baranowska K, Wojnowski W (2008) Acta Cryst E 64:m46CrossRefGoogle Scholar
  29. 29.
    Sheldrick GM (2008) Acta Crystallogr Sect A Found Crystallogr 64:112CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2010

Authors and Affiliations

  • Agnieszka Pladzyk
    • 1
    Email author
  • Katarzyna Baranowska
    • 1
  • Patrycja Hapter
    • 1
  1. 1.Department of Inorganic ChemistryUniversity of TechnologyGdańskPoland

Personalised recommendations