Transition Metal Chemistry

, 34:861 | Cite as

Pyridine-2,5-dicarboxylic acid complexes of nickel(II) with 2,2′-bipyridine and 1,10-phenanthroline coligands; syntheses, crystal structures, spectroscopic and thermal studies

  • Alper Tolga Çolak
  • Demet Akduman
  • Okan Zafer Yeşilel
  • Orhan Büyükgüngör


Two pyridine-2,5-dicarboxylic acid (pydcH2) complexes of nickel(II) with 2,2′-bipyridine and 1,10-phenanthroline were synthesized and characterized by elemental, spectroscopic, thermal analysis, magnetic measurements and single crystal X-ray diffraction techniques. Both [Ni(pydc)(bipy)2]·7H2O and [Ni(pydc)(phen)2]·6.5H2O crystallize in the monoclinic system and P21/c space group. The Ni(II) ions are coordinated by two bidentate bipy or phen ligands and one pydc dianion in a distorted octahedral geometry. The pydc ligand is coordinated through the pyridine nitrogen atom and oxygen atom of carboxyl group as a bidentate ligand. Both carboxylate groups of pydc are deprotonated but only the 2-carboxylate is coordinated to the metal. Thermal decompositions of the complexes have been studied over the range 30–600 °C on heating in a static air atmosphere.


Phen Bipy Bipyridine Pyridine Ring Distorted Octahedral Geometry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



This work was supported by the Dumlupinar University by project No 2007/14.


  1. 1.
    Silva MR, Silva PSP, Beja AM, Paixao JA, Justino LLG, Sobral AJFN (2007) J Mol Struct 837:58CrossRefGoogle Scholar
  2. 2.
    Haitao X, Nengwu Z, Hanhui X, Yonggang W, Rui Y, Enyi Y, Xianglin J (2001) J Mol Struct 597:1CrossRefGoogle Scholar
  3. 3.
    Lee JS, Shim HS, Park YS, Park SJ, Shin JS, Yang WY, Lee HD, Park WJ, Chung YH, Lee SW (2002) Bioorg Med Chem Lett 12:2715CrossRefGoogle Scholar
  4. 4.
    Fink GS, Cuervo LG, Therrien B, Stoeckli-Evans H, Shul’pin GB (2004) Inorg Chim Acta 357:475CrossRefGoogle Scholar
  5. 5.
    Sengupta P, Ghosh S, Mak TCW (2001) Polyhedron 20:975CrossRefGoogle Scholar
  6. 6.
    Tucker H, Thomas DF (1992) J Med Chem 35:804CrossRefGoogle Scholar
  7. 7.
    Kita E, Marai H, Zaja K (2008) Trans Met Chem 33:211CrossRefGoogle Scholar
  8. 8.
    Sun LP, Niu SY, Jin J, Yang GD, Ye L (2006) Eur J Inorg Chem 2006:5130CrossRefGoogle Scholar
  9. 9.
    Patrick BO, Stevens CL, Storr A, Thompson RC (2005) Polyhedron 24:2242CrossRefGoogle Scholar
  10. 10.
    Min D, Yoon SS, Jung DY, Lee CY, Kim Y, Han WS, Lee SW (2001) Inorg Chim Acta 324:293CrossRefGoogle Scholar
  11. 11.
    Kumagai H, Sobukawa H, Kurmoo M (2008) J Mater Sci 43:2123CrossRefGoogle Scholar
  12. 12.
    Zhang DJ, Song TY, Wang L, Shi J, Xu JN, Wang Y, Ma KR, Yin WR, Zhang LR, Fan Y (2009) Inorg Chim Acta 362:299. doi: 10.1016/j.ica.2008.03.103 CrossRefGoogle Scholar
  13. 13.
    Liang Y, Hong M, Su W, Cao R, Zhang W (2001) Inorg Chem 40:4574CrossRefGoogle Scholar
  14. 14.
    Song Y, Yan B, Chen Z (2005) J Coord Chem 58:811CrossRefGoogle Scholar
  15. 15.
    Zhang G, Wang Q, Qian Y, Yang G, Ma JS (2006) J Mol Struct 796:187CrossRefGoogle Scholar
  16. 16.
    Song YS, Yan B, Chen ZX (2005) J Mol Struct 750:101CrossRefGoogle Scholar
  17. 17.
    Yang M, Wang L, Li G, Yang L, Shi Z, Feng S (2007) J Alloy Comp 440:57CrossRefGoogle Scholar
  18. 18.
    Akhbari K, Morsali A (2008) J Mol Struct 878:65CrossRefGoogle Scholar
  19. 19.
    Zhang X, Huang D, Chen C, Liu Q, Liao D, Li L (2005) Inorg Chem Commun 8:22CrossRefGoogle Scholar
  20. 20.
    Yao YW, Lin HX, Sun XD, Kou HZ, Cai Q, Li HD, Yu RB, Wang D (2005) Trans Met Chem 30:294CrossRefGoogle Scholar
  21. 21.
    Zeng MH, Gao S, Yua XL, Chen XM (2003) New J Chem 27:1599CrossRefGoogle Scholar
  22. 22.
    Xie C, Zhang B, Wang X, Wang R, Shen G, Shen D (2007) J Chem Crystallogr 37:25CrossRefGoogle Scholar
  23. 23.
    Plater MJ, Foreman MRSJ, Howie RA, Lachowski EE (1998) J Chem Res (S) 754–755Google Scholar
  24. 24.
    Tian G, Zhu G, Yang X, Fang Q, Xue M, Sun J, Wei Y, Qiu S (2005) Chem Commun 1396–1398Google Scholar
  25. 25.
    Jung EJ, Lee UK, Koo BK (2008) Inorg Chim Acta 361:2962CrossRefGoogle Scholar
  26. 26.
    Min D, Yoon SS, Lee CY, Han WS, Lee S (2001) Bull Korean Chem Soc 22:1041Google Scholar
  27. 27.
    Wei Y, Hou H, Li L, Fan Y, Zhu Y (2005) Cryst Growth Des 5:1405CrossRefGoogle Scholar
  28. 28.
    Mahata P, Natarajan S (2005) Eur J Inorg Chem 2005:2156CrossRefGoogle Scholar
  29. 29.
    Natarajan S, Mandal S, Mahata P, Rao VK, Ramaswamy P, Banarjee A, Paul AK, Ramya KV (2006) J Chem Sci 118:525CrossRefGoogle Scholar
  30. 30.
    Sileo EE, Piro OE, Rigotti G, Blesa MA, Araujo ASD, Castellano EE (2008) Struct Chem 19:651CrossRefGoogle Scholar
  31. 31.
    Wen L, Lu Z, Lin J, Tian Z, Zhu H, Meng Q (2007) Cryst Growth Des 7:93CrossRefGoogle Scholar
  32. 32.
    Che GB, Wang J, Sun J, Lu L, Yu ZX (2006) Acta Crystallogr E62:m3257Google Scholar
  33. 33.
    Gao DZ, Jiang ZH, Liao DZ (2005) Acta Crystallogr E61:m2446Google Scholar
  34. 34.
    Choi KY, Chun KM, Suh IH (2001) Polyhedron 20:57CrossRefGoogle Scholar
  35. 35.
    Goher MAS, Youssef AA, Mautner FA (2006) Polyhedron 25:1531CrossRefGoogle Scholar
  36. 36.
    Che GB, Liu CB (2006) Acta Crystallogr E62:m1728Google Scholar
  37. 37.
    Basiuk EV, Basiuk VV, Lara JG, Toscano RA (2000) J Inc Phen Macro Chem 38:45CrossRefGoogle Scholar
  38. 38.
    Zhao SM, Wu TX (2006) Acta Crystallogr E62:m508Google Scholar
  39. 39.
    Sheldrick GM (1997) SHELXS97 and SHELXL97. University of Göttingen, GöttingenGoogle Scholar
  40. 40.
    Sheldrick GM (1997) SHELXL-97, program for crystal structure refinement. University of Göttingen, GöttingenGoogle Scholar
  41. 41.
    Stoe&Cie (2002) X-Area (Version 1.18) and X-Red32 (Version 1.04). Stoe&Cie, DarmstadtGoogle Scholar
  42. 42.
    Farrugia LJ (1997) J Appl Crystallogr 30:565CrossRefGoogle Scholar
  43. 43.
    Farrugia LJ (1999) WinGX—a windows program for crystal structure analysis. J Appl Crystallogr 32:837CrossRefGoogle Scholar
  44. 44.
    Spek AL (2003) J Appl Crystallogr 23:7CrossRefGoogle Scholar
  45. 45.
    Puntus L, Zolin V, Kudryashova V (2004) J Alloys Comp 374:330CrossRefGoogle Scholar
  46. 46.
    Gao HL, Cheng C, Ding B, Shi W, Song HB, Cheng P, Liao DZ, Yan SP, Jiang ZH (2005) J Mol Struct 738:105CrossRefGoogle Scholar
  47. 47.
    Yesilel OZ, Olmez H (2006) J Therm Anal Cal 86:211CrossRefGoogle Scholar
  48. 48.
    Yesilel OZ, Olmez H, Icbudak H (2007) J Therm Anal Cal 89:555CrossRefGoogle Scholar
  49. 49.
    Shiu KB, Chen ZW, Liao FL, Wang SL (2003) Acta Crystallogr E59:m1072Google Scholar
  50. 50.
    Aghabozorg H, Derikvand Z, Nemati A, Ghadermazi M (2007) Acta Crystallogr E63:m2919Google Scholar

Copyright information

© Springer Science+Business Media B.V. 2009

Authors and Affiliations

  • Alper Tolga Çolak
    • 1
  • Demet Akduman
    • 1
  • Okan Zafer Yeşilel
    • 2
  • Orhan Büyükgüngör
    • 3
  1. 1.Department of Chemistry, Faculty of Arts and SciencesDumlupınar UniversityKütahyaTurkey
  2. 2.Department of Chemistry, Faculty of Arts and SciencesEskişehir Osmangazi UniversityEskişehirTurkey
  3. 3.Department of Physics, Faculty of Arts and SciencesOndokuz Mayıs UniversityKurupelitTurkey

Personalised recommendations