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Structural characterization of a novel self-assembly heterohexanuclear complex: [Ni2Ag4(μ-dppm)4(pymt)6](SbF6)2 · 2DMF · H2O

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Abstract

A novel heterohexanuclear complex [Ni2Ag4(μ-dppm)4(pymt)6](SbF 6)2 · 2DMF · H2O (1), was synthesized by self-assembly with [Ag2(μ-dppm)2(MeCN)2](SbF6) 2 and [Et4N][Ni(pymt)3] (dppm = bis(diphenylphosphino)methane, pymt = pyrimidine-2-thiolate) as components and characterized by IR spectra, elemental analysis, 1H-NMR spectrum, 31P-NMR spectrum and Visible-Ultraviolet spectrum. Structure of the complex was determined by X-ray analysis.

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Correspondence to Hong-wu Xu.

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Xu, H., Pin, L., Li, J. et al. Structural characterization of a novel self-assembly heterohexanuclear complex: [Ni2Ag4(μ-dppm)4(pymt)6](SbF6)2 · 2DMF · H2O. Transition Met Chem 32, 781–783 (2007). https://doi.org/10.1007/s11243-007-0251-1

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Keywords

  • MeCN
  • Silver Atom
  • Dppm
  • Diphenylphosphino
  • Diphosphines