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Transition Metal Chemistry

, Volume 29, Issue 6, pp 644–648 | Cite as

Ruthenium(II) complexes containing triphenylphosphine/triphenylarsine and bidentate Schiff bases derived from 2-hydroxy-1-naphthaldehyde and primary amines

  • Kugalur P. Balasubramanian
  • Vaiapuri Chinnusamy
  • Ramasamy Karvembu
  • Karuppannan Natarajan
Article

Abstract

The synthesis and characterisation of some new hexa-coordinated Schiff base complexes of the type [RuCl(CO)(EPh3)(B)(L)] (E = P or As; B = PPh3 or AsPh3 or py or pip; L = anion of the Schiff bases derived from 2-hydroxy-1-naphthaldehyde and aniline, 4-chloroaniline or 2-methylaniline) are reported. I.r., electronic, 1H-n.m.r, 31P-n.m.r. spectra, catalytic activity and antibacterial activity of the complexes are discussed. An octahedral structure has been tentatively proposed for all the complexes.

Keywords

Physical Chemistry Inorganic Chemistry Catalysis Catalytic Activity Antibacterial Activity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Kluwer Academic Publishers 2004

Authors and Affiliations

  • Kugalur P. Balasubramanian
    • 1
  • Vaiapuri Chinnusamy
    • 1
  • Ramasamy Karvembu
    • 2
  • Karuppannan Natarajan
    • 2
  1. 1.Department of ChemistrySri Ramakrishna Mission Vidyalaya College of Arts and ScienceCoimbatoreIndia
  2. 2.Department of ChemistryBharathiar UniversityCoimbatoreIndia

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