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Template synthesis in the nickel(II)–thiocarbohydrazide–propanone triple system

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Abstract

The complexing process proceeding in the NiII–thiocarbohydrazide (H2N–H–NC(=S)–NH–NH2)–propanone triple system in EtOH solution and nickel(II)hexacyanoferrate(II) gelatin-immobilized matrix has been studied. It has been found that in the first case, template synthesis leading, as a minimum, to formation of three coordination compounds of NiII with (N,N,S,S)-donor tetradentate ligands having NiL1, NiL2 and NiL3compositions where L1 is 4,6,6-trimethyl-2,3,7,8-tetraazanonen-3-di(thiohydrazide)-1,9, L2 is 4,6,6,12-tetrametyl-1,9-dithio-2,3,7,8,10,11-hexaazatridekadien-3,11-hydrazide-1 and L3 is 2,8,10,10,16-pentamethyl-5,13-dithio-3,4,6,7,11,12,14,15-octaazaheptadekatrien-2,7,15 is observed, whereas in the gelatin-immobilized matrix, a complexing process in the system considered does not occur.

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Correspondence to Oleg V. Mikhailov.

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Mikhailov, O.V., Kazymova, M.A., Shumilova, T.A. et al. Template synthesis in the nickel(II)–thiocarbohydrazide–propanone triple system. Transition Met Chem 30, 299–304 (2005). https://doi.org/10.1007/s11243-004-4577-7

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Keywords

  • Physical Chemistry
  • Nickel
  • Propanone
  • Inorganic Chemistry
  • Catalysis