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Effect of the Size of Polyacrylamide-Stabilized Palladium Nanoparticles Supported on γ-Fe2O3 on Their Catalytic Properties in the Hydrogenation of Phenylacetylene

  • E. T. TalgatovEmail author
  • A. S. Auyezkhanova
  • K. S. Seitkalieva
  • S. N. Akhmetova
  • A. K. Zharmagambetova
Article
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Hydrogenation catalysts derived from palladium nanoparticles varying in size supported on maghemite (γ-Fe2O3) were obtained by varying the concentration of K2PdCl4 and polyacrylamide as well as the solution pH during catalyst preparation. These catalysts were characterized by electron microscopy, dynamic light scattering, energy dispersive analysis, and IR spectroscopy. Decreasing the size of the palladium nanoparticles leads to enhanced activity of the catalyst in the hydrogenation of phenylacetylene by molecular hydrogen

Key words

nanoparticles palladium polyacrylamide maghemite supported catalyst hydrogenation phenylacetylene 

References

  1. 1.
    A. K. Zharmagambetova, A. S. Auyezkhanova, and É. T. Talgatov, Metal-Polymer Catalysts in Liquid-Phase Processes [in Russian], D. V. Sokolsky Institute of Fuel, Catalysis and Electrochemistry, Almaty (2018).Google Scholar
  2. 2.
    N. Kann, Molecules, 15, 6306-6331 (2010).CrossRefGoogle Scholar
  3. 3.
    N. Sahiner, Progr. Polym. Sci., 38, No. 9, 1329-1356 (2013).CrossRefGoogle Scholar
  4. 4.
    M. Michela Dell’Anna, G. Romanazzi, and P. Mastrorilli, Curr. Org. Chem., 17, 1236-1273 (2013).CrossRefGoogle Scholar
  5. 5.
    H. Hu, J. Xin, H. Hu, et al., J. Mater. Chem. A, 3, 11157-11182 (2015).CrossRefGoogle Scholar
  6. 6.
    S. Li, P. Lieberzeit, S. Piletsky, and A. Turner (eds.), Smart Polymer Catalysts and Tunable Catalysis, Elsevier, Amsterdam (2019).Google Scholar
  7. 7.
    R. Roa, S. Angioletti-Uberti, Y. Lu, et al., Z. Phys. Chem., 232, Nos. 5/6, 773-803 (2018).CrossRefGoogle Scholar
  8. 8.
    M. Liu, J. Zhang, M. Han, and J. Liu, Synth. React. Inorg., Metal-Org., Nano-Metal Chem., 40, No. 10, 785-789 (2010).CrossRefGoogle Scholar
  9. 9.
    B. L. Albuquerque, A. Denicourt-Nowicki, C. Mériadec, et al., J. Catal., 340, 144-153 (2016).CrossRefGoogle Scholar
  10. 10.
    T. Bortolotto, S. E. Facchinetto, S. G. Trindade, et al., J. Colloid Interface Sci., 439, 154-161 (2015).CrossRefGoogle Scholar
  11. 11.
    C.-J. Jia and F. Schuth, Phys. Chem. Chem. Phys., 13, 2457-2487 (2011).CrossRefGoogle Scholar
  12. 12.
    I. Beletskaya and V. Tyurin, Molecules, 15, 4792-4814 (2010).CrossRefGoogle Scholar
  13. 13.
    K. Gude, Synthesis, Characterization and Applications of Colloidal-Supported Metal Nanoparticles, University of Rhode Island, Kingston (2011).Google Scholar
  14. 14.
    E. Gross, F. Dean Toste, and G. A. Somorjai, Catal. Lett., 145, No. 1, 126-138 (2015).CrossRefGoogle Scholar
  15. 15.
    X. Cui, W. Li, P. Ryabchuk, et al., Nat. Catal., 1, No. 6, 385-397 (2018).CrossRefGoogle Scholar
  16. 16.
    A. K. Zharmagambetova, E. T. Talgatov, A. S. Auyezkhanova, et al., Teor. Éksp. Khim., 54, No. 4, 244-250 (2018). [Theor. Exp. Chem., 54, No. 4, 265-273 (2018) (English translation).]Google Scholar
  17. 17.
    I. B. Bychko, Ye. Yu. Kalishyn, Z. V. Kaidanovych, et al., Teor. Éksp. Khim., 54, No. 5, 326-330 (2018). [Theor. Exp. Chem., 54, No. 5, 358-363 (2018) (English translation).]Google Scholar
  18. 18.
    A. M. Abu-Dief and S. M. Abdel-Fatah, Beni-Suef Univ. J. Basic Appl. Sci., 7, 55-67 (2018).CrossRefGoogle Scholar
  19. 19.
    J. Govan and Y. K. Gun’ko, Nanomaterials, 4, 222-241 (2014).CrossRefGoogle Scholar
  20. 20.
    L. M. Rossi, N. J. S. Costa, F. P. Silva, and R. Wojcieszak, Green Chem., 16, 2906-2933 (2014).CrossRefGoogle Scholar
  21. 21.
    E. T. Talgatov, A. S. Auyezkhanova, N. Z. Tumabayev, et al., News of NAS RK, Ser. Chem. Technol., 6, No. 5, 29-37 (2018).CrossRefGoogle Scholar
  22. 22.
    A. K. Zharmagambetova, K. S. Seitkalieva, E. T. Talgatov, et al., Kinet. Catal., 57, 360-367 (2016).CrossRefGoogle Scholar
  23. 23.
    S. Ahmed, M. A. Sheraz, and L. U. Rehman, AAPS PharmSciTech, 14, 870-879 (2013)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • E. T. Talgatov
    • 1
    Email author
  • A. S. Auyezkhanova
    • 1
  • K. S. Seitkalieva
    • 1
  • S. N. Akhmetova
    • 1
  • A. K. Zharmagambetova
    • 1
  1. 1.D. V. Sokolsky Institute of Fuel, Catalysis and ElectrochemistryAlmatyRepublic of Kazakhstan

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