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Effect of Acid–Base Characteristics of In2O3-Al2O3 (ZrO2) Compositions on Their Catalytic Properties in the Oxidative Dehydrogenation of Propane to Propylene with CO2

  • M. R. KantserovaEmail author
  • N. V. Vlasenko
  • S. M. Orlyk
  • K. Veltruska
  • I. Matolinova
Article
  • 5 Downloads

The effect of the nature of the support and the method of preparation of indium–aluminum(zirconium) oxide compositions on their acid–base characteristics, which determine the catalytic activity in oxidative dehydrogenation of propane with participation of CO2, was established. The highest selectivity for propylene (51%) is achieved over the In2O3–Al2O3 catalyst, which is due to the presence on its surface of stronger Lewis acid sites for activation of C3H8 and to a higher concentration of base sites for activation of CO2.

Key words

propylene oxidative dehydrogenation of propane CO2 indium oxide aluminium oxide zirconium dioxide acid–base characteristics 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • M. R. Kantserova
    • 1
    Email author
  • N. V. Vlasenko
    • 1
  • S. M. Orlyk
    • 1
  • K. Veltruska
    • 2
  • I. Matolinova
    • 2
  1. 1.L. V. Pysarzhevsky Institute of Physical ChemistryNational Academy of Sciences of UkraineKyivUkraine
  2. 2.Charles University, Department of Surface and Plasma Science V. Holesovickach 747/2Prague 8Czech Republic

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