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Effect of Production Conditions of Hierarchical SnAl-BEA Zeolites on Their Acidity and Catalytic Activity in Tandem Process for the Production of 4-Methoxybenzyl-sec-Butyl Ether

  • M. M. KurmachEmail author
  • N. O. Popovych
  • P. I. Kyriienko
  • P. S. Yaremov
  • O. Y. Khyzhun
  • O. V. Andreev
  • O. V. Shvets
Article
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Hierarchical SnAl-silicate zeolites of the BEA structural type with Lewis (up to 130 μmol/g) and Brønsted (up to 330 μmol/g) acid sites, the concentration of which according to diffuse reflectance and X-ray photoelectron spectroscopy increases with increase of the charge of the hydrophilic part of the employed templates and also the Al3+ and Sn4+ contents, were obtained. In the catalytic tandem process in the presence of the obtained zeolites 89%-99% selectivity for 4-methoxybenzyl-sec-butyl ether and 36% conversion for anisaldehyde are obtained.

Key words

hierarchical zeolites SnAl-BEA structure-directing agents acid sites Meerwein–Ponndorf–Verley reaction 

References

  1. 1.
    A. Al-Nayili, K. Yakabi, and C. Hammond, J. Mater. Chem. A, 4, 1373-1382 (2016).CrossRefGoogle Scholar
  2. 2.
    A. Corma, L. T. Nemeth, M. Renz, and S. Valencia, Nature, 412, 423-425 (2001).CrossRefGoogle Scholar
  3. 3.
    J. Prech, M. Arroyo Carretero, and J. Èejka, ChemCatChem, 9, No. 15, 3063-3072 (2017).CrossRefGoogle Scholar
  4. 4.
    A. Corma, M. E. Domine, L. Nemeth, and S. Valencia, J. Am. Chem. Soc., 124, 3194-3195 (2002).CrossRefGoogle Scholar
  5. 5.
    K. R. Reddy, M. Suresh, M. L. Kantam, et al., Ind. Eng. Chem. Res., 53, 18630-18636 (2014).CrossRefGoogle Scholar
  6. 6.
    M. Choi, K. Na, J. Kim, et al., Nature, 461, 246-249 (2009).CrossRefGoogle Scholar
  7. 7.
    L.Wang, J. Zhang, X. Wang, et al., J. Mater. Chem. A, 2, 3725 (2014).CrossRefGoogle Scholar
  8. 8.
    J. Dijkmans, M. Dusselier, D. Gabri¸ls, et al., ACS Catal., 5, 928-940 (2015).CrossRefGoogle Scholar
  9. 9.
    L. Li, J. Ding, J.-G. Jiang, et al., Chinese J. Catal., 36, 820-828 (2015).CrossRefGoogle Scholar
  10. 10.
    M. J. Climent, A. Corma, and S. Iborra, ChemSusChem, 2, 500-506 (2009).CrossRefGoogle Scholar
  11. 11.
    A. Corma and M. Renz, Angew. Chem., 119, 302-304 (2007).CrossRefGoogle Scholar
  12. 12.
    M. M. Kurmach, N. O. Popovych, P. I. Kyriienko, et al., Teor. Éksp. Khim., 53, No. 2, 114-120 (2017). [Theor. Exp. Chem., 53, No. 2, 122-129 (2017) (English translation).]Google Scholar
  13. 13.
    M. N. Kurmach, P. S. Yaremov, and V. V. Tsyrina, Teor. Éksp. Khim., 51, No. 4, 211-218 (2015). [Theor. Exp. Chem., 51, No. 4, 216-223 (2015) (English translation).]Google Scholar
  14. 14.
    K. Cho, K. Na, J. Kim, et al., Chem. Mater., 24, 2733-2738 (2012).CrossRefGoogle Scholar
  15. 15.
    C. A. Emeis, J. Catal., 141, 347-354 (1993).CrossRefGoogle Scholar
  16. 16.
    K. M. Konysheva, T. M. Boichuk, and O. V. Shvets, Teor. Éksp. Khim., 52, No. 2, 89-95 (2016). [Theor. Exp. Chem., 52, No. 2, 90-96 (2016) (English translation).]Google Scholar
  17. 17.
    P. Li, G. Liu, H. Wu, et al., J. Phys. Chem. C, 115, 3663-3670 (2011).CrossRefGoogle Scholar
  18. 18.
    B. Tang, W. Dai, G. Wu, et al., ACS Catal., 4, 2801-2810 (2014).CrossRefGoogle Scholar
  19. 19.
    M. P. Pachamuthu, K. Shanthi, R. Luque, and A. Ramanathan, Green Chem., 15, 2158-2166 (2015).CrossRefGoogle Scholar
  20. 20.
    X. Ouyang, S.-J. Hwang, D. Xie, et al., ACS Catal., 5, 3108-3119 (2015).CrossRefGoogle Scholar
  21. 21.
    B.-T. Lønstad Bleken, L. Mino, F. Giordanino, et al., Phys. Chem. Chem. Phys., 15, 13363 (2013).CrossRefGoogle Scholar
  22. 22.
    R. Barakov, N. Shcherban, P. Yaremov, et al., Micropor. Mesopor. Mater., 237, 90-107 (2017).CrossRefGoogle Scholar
  23. 23.
    N. O. Popovych, P. I. Kyriienko, Y. Millot, et al., Micropor. Mesopor. Mater., 268, 178-188 (2018).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • M. M. Kurmach
    • 1
    Email author
  • N. O. Popovych
    • 1
  • P. I. Kyriienko
    • 1
  • P. S. Yaremov
    • 1
  • O. Y. Khyzhun
    • 2
  • O. V. Andreev
    • 3
  • O. V. Shvets
    • 1
  1. 1.L.V. Pysarzhevsky Institute of Physical ChemistryNational Academy of Sciences of UkraineKyivUkraine
  2. 2.Institute for Problems of Materials ScienceNational Academy of Sciences of UkraineKyivUkraine
  3. 3.Taras Shevchenko National University of KyivKyivUkraine

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