Theoretical and Experimental Chemistry

, Volume 53, Issue 1, pp 17–24 | Cite as

Features of Cooperative Adsorption Described by Sticking Probability that Depends on the Number of Neighbors

  • E. G. Manoilov
  • S. A. Kravchenko
  • B. A. Snopok
Article
First Online:
Received:
Revised:
  • 45 Downloads

The kinetic curves and monolayer clusters on a flat surface for cooperative adsorption, where the probability of sticking of the particles depends on the amount of neighbors on the surface, were calculated by nonequilibrium molecular dynamics. It was found that the type of distribution of the sticking coefficients has a large effect both on the dynamic and on the structural characteristics of the adsorption process. It is shown that the most informative algorithm for classifying the adsorption type is based on the dependence of the fractal dimensionality of the surface structure on the degree of surface coverage.

Key words

cooperative adsorption lateral interactions molecular dynamics fractal analysis kinetics topographic investigations self-similar surface organization 
This is a preview of subscription content, log in to check access.

References

  1. 1.
    A. Dabrowski, Adv. Colloid Interface Sci., 93, 135-224 (2001).CrossRefGoogle Scholar
  2. 2.
    I. Ya. Myasnikov, V. Ya. Sukharev, L. Yu. Kupriyanov, and S. A. Zav’yalov, Semiconducting Sensors in Physicochemical Investigations [in Russian], Nauka, Moscow (1991).Google Scholar
  3. 3.
    V. L. Gromashevskii, N. P. Tat’yanenko, and B. A. Snopok, Teor. Éksp. Khim., 51, No. 3, 163-170 (2015). [Theor. Exp. Chem., 50, No. 3, 170-176 (2015) (English translation).]Google Scholar
  4. 4.
    X. Hu, S. L. Crick, G. Bu, et al., PNAS, 106, 20324-20329 (2009).CrossRefGoogle Scholar
  5. 5.
    H. A. Videla and L. K. Herrera, Int. Microbiology, 8, 169-180 (2005).Google Scholar
  6. 6.
    B. Leimkuhler and C. Matthews, Molecular Dynamics: with Deterministic and Stochastic Numerical Methods, Springer, London (2015).Google Scholar
  7. 7.
    H. D. Höltje, W. Sippl, D. Rognan, and G. Folkers, Molecular Modeling (Theory and Practice) [Russian translation], Laboratoriya Znanii BINOM, Moscow (2010).Google Scholar
  8. 8.
    Y. K. Tovbin (ed.), Molecular Dynamics Method in Physical Chemistry [in Russian], Nauka, Moscow (1996).Google Scholar
  9. 9.
    L. Guo, L. Xiao, X. Shan, and X. Zhang, Sci. Rep., 6, 27134 (2016).CrossRefGoogle Scholar
  10. 10.
    B. Chopard and M. Droz, Cellular Automata Modeling of Physical Systems, Cambridge Univ. Press, New York (2005).Google Scholar
  11. 11.
    E. G. Manoilov, S. A. Kravchenko, and B. A. Snopok, Optoelektron. Poluprovodn. Tekhn., 51, 135-142 (2016).Google Scholar
  12. 12.
    B. A. Snopok, P. N. Boltovets, and F. J. Rowell, Teor. Éksp. Khim., 42, No. 2, 96-101 (2006). [Theor. Exp. Chem., 42, No. 2, 106-112 (2006) (English translation).]Google Scholar
  13. 13.
    B. A. Snopok, Teor. Éksp. Khim., 48, No. 5, 265-285 (2012). [Theor. Exp. Chem., 48, No. 5, 283-306 (2012) (English translation).]Google Scholar
  14. 14.
    B. B. Mandelbrot, The Fractal Geometry of Nature, Freeman, San Francisco (1982).Google Scholar
  15. 15.
    E. Feder, Fractals [Russian translation], Mir, Moscow (1991).Google Scholar
  16. 16.
    B. M. Smirnov, Physics of Fractal Clusters [in Russian], Nauka, Moscow (1991).Google Scholar
  17. 17.
    B. A. Snopok, P. E. Strizhak, E. V. Kostyukevich, et al., Semicond. Phys. Quantum Electron. Optoelectron., 2, No. 3, 86-97 (1999).Google Scholar
  18. 18.
    P. E. Strizhak, B. A. Snopok, T. Melnik, et al., Proc. of SPIE, 3904, 374-385 (1999) (DOI  10.1117/12.370427).CrossRefGoogle Scholar
  19. 19.
    K. Falconer, Fractal Geometry: Mathematical Foundations and Applications, John Wiley, Chichester (1990).Google Scholar
  20. 20.
    B. A. Snopok, Teor. Éksp. Khim., 50, No. 2, 69-93 (2014). [Theor. Exp. Chem., 50, No. 2, 67-95 (2014) (English translation).]Google Scholar

Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  • E. G. Manoilov
    • 1
  • S. A. Kravchenko
    • 1
  • B. A. Snopok
    • 1
  1. 1.V. E. Lashkaryov Institute of Semiconductors PhysicsNational Academy of Sciences of UkraineKyivUkraine

Personalised recommendations