Theoretical and Experimental Chemistry

, Volume 51, Issue 2, pp 96–103 | Cite as

Visible Light Photocatalytic Oxidation of Ethanol Vapor on Titanium Dioxide Modified with Noble Metals

Article

The kinetics of photocatalytic oxidation of ethanol vapors under visible light (\( \lambda \)> 420 nm) on the TiO2 modified with noble metal (Au and Ag) and ions (Pt, Pd and Ru) is studied. The effect of the modificator on the activity of Au/TiO2 and Pt/TiO2 photocatalysts is studied. The optimum metal content is ~1 wt.%. The quantum efficiency is calculated for all the samples. The photocatalytic activity of the studied samples is compared with activity of the commercial sample of Kronos vlp7000. The dependence of Ag/TiO2 catalytic activity on the silver ion reduction method is shown.

Key words

photocatalysis visible light titanium dioxide ethanol 

References

  1. 1.
    X. Chen and S. S. Mao, Chem. Rev., 107, No. 7, 2891–2959 (2007).CrossRefGoogle Scholar
  2. 2.
    N. Serpone, Sol. Energ. Mat. Sol. C, 38, Nos. 1–4, 369–379 (1995).CrossRefGoogle Scholar
  3. 3.
    B. O’Regan and M. Gratzel, Nature, 353, 737–740 (1991).CrossRefGoogle Scholar
  4. 4.
    J. He, G. Benko, F. Korodi, et al., J. Am. Chem. Soc., 124, 4922–4932 (2002).CrossRefGoogle Scholar
  5. 5.
    R. Asahi, T. Morikawa, T. Ohwaki, et al., Science, 293, 269–271 (2001).CrossRefGoogle Scholar
  6. 6.
    Z. Zou, J. Ye, H. Sayama, and H. Arakawa, Nature, 414, 625–627 (2001).CrossRefGoogle Scholar
  7. 7.
    K. Maeda, K. Teramura, D. Lu, et al., Nature, 440, 295 (2006).CrossRefGoogle Scholar
  8. 8.
    A. V. Vorontsov, E. A. Kozlova, A. S. Besov, et al., Kinet. Katal., 51, No. 6, 829–836 (2010).CrossRefGoogle Scholar
  9. 9.
    P. A. Kolinko, D. V. Kozlov, A. V. Vorontsov, and S. V. Preis, Catal. Today, 122, 178–185 (2007).CrossRefGoogle Scholar
  10. 10.
    Z. Yang, J. Li, H. Zhang, et al., Catal. Sci. Technol. (2015), Advance Article, DOI: 10.1039/c4cy01384k.
  11. 11.
    J. Choi, H. Park, and M. R. Hoffmann, J. Phys. Chem. C, 114, 783–792 (2010).Google Scholar
  12. 12.
    S. Ismat Shah, C. P. Huang, J. G. Chen, et al., NSF Nanoscale Sci. and Eng. Grantees Conference, Dec. 16–18, 003, Grant No. 0210284.Google Scholar
  13. 13.
    O. Carp, C. L. Huisman, and A. Reller, Progr. Solid State Chem., 32, 33–177 (2004).CrossRefGoogle Scholar
  14. 14.
    M. L. Sauer and D. F. Ollis, J. Catal., 158, 570–582 (1996).CrossRefGoogle Scholar
  15. 15.
    M. Nimlos, E. Wolfrum, M. Brewer, et al., Environ. Sci. Technol., 30, 3102–3110 (1996).CrossRefGoogle Scholar
  16. 16.
    A. A. Gorenberg, New Nanobiomaterials from Titanium Dioxide and Their Use as Photocatalysts [in Russian], Dissertation in competition for the academic degree of Candidate of the Chemical Sciences, Moscow (2009).Google Scholar
  17. 17.
    Z. Liu, W. Hou, P. Pavaskar, et al., Nano Lett., 11, 1111–1116 (2011).CrossRefGoogle Scholar
  18. 18.
    É. L. Nagaev, Usp. Fiz. Nauk, 162, No. 9, 50–119 (1992).CrossRefGoogle Scholar
  19. 19.
    M. S. Devadas, K. Kwak, J.-W. Park, et al., J. Phys. Chem. Lett., 1, No. 9, 1497–1503 (2010).CrossRefGoogle Scholar
  20. 20.
    S. Mubeen, G. Hernandez-Sosa, D. Moses, et al., Nano Lett., 11, No. 12, 5548–5552 (2011).CrossRefGoogle Scholar
  21. 21.
    C. G. Silva, R. Juarez, T. Marino, et al., J. Am. Chem. Soc., 133, No. 3, 595–602 (2011).CrossRefGoogle Scholar
  22. 22.
    A. I. Kryukov, A. L. Stroyuk, C. Ya. Kuchmii, and V. D. Pokhodenko, Nanophotocatalysis, V. G. Koshechko ed.), Akademperiodika, Kiev (2013).Google Scholar
  23. 23.
    C. M. Wang, A. Heller, and H. Gerischer, J. Am. Chem. Soc., 114, 5230–5234 (1992).CrossRefGoogle Scholar
  24. 24.
    H. Gerischer and A. Heller, J. Phys. Chem., 95, 5261–5267 (1991).Google Scholar
  25. 25.
    T. Kobayashi, H. Yoneyama, and H. Tamura, J. Electrochem. Soc., 103, 1706–1711 (1983).Google Scholar
  26. 26.
    B. Krautler and A. J. Bard, J. Am. Chem. Soc., 100, 5985–5989 (1978).CrossRefGoogle Scholar
  27. 27.
    I. Izumi, W. W. Dumm, K. O. Wilbourn, et al., J. Phys. Chem., 84, 3207–3210 (1980).CrossRefGoogle Scholar
  28. 28.
    P. A. Kolinko and D. V. Kozlov, Environ. Sci. Technol., 42, 4350–4355 (2008). 103Google Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • P. A. Kolinko
    • 1
    • 2
    • 3
  • D. S. Selishchev
    • 1
    • 2
    • 3
  • D. V. Kozlov
    • 1
    • 2
    • 3
  1. 1.Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of SciencesNovosibirskRussian Federation
  2. 2.Novosibirsk State UniversityNovosibirskRussian Federation
  3. 3.Research and Educational Center for Energy Efficient CatalysisNovosibirsk State UniversityNovosibirskRussian Federation

Personalised recommendations