Theoretical and Experimental Chemistry

, Volume 49, Issue 4, pp 235–240 | Cite as

Luminescent properties of europium-doped zinc formate and oxide

  • I. V. Baklanova
  • V. N. Krasil’nikov
  • L. A. Perelyaeva
  • O. I. Gyrdasova
Article
First Online:
Received:
  • 119 Downloads

Europium-doped zinc formate was synthesized by crystallization from a solution prepared by the reaction of the diluted formic acid on a mixture of ZnO and Eu2O3, Zn1–x Eu x (HCOO)2+x ∙2H2O (0.005 ≤ x ≤ 0.05) under heating. Thermolysis of Zn1–x Eu x (HCOO)2+x ∙2H2O gave Zn1–x Eu x O1+x with no more than 2.5 at.% degree of replacement of zinc by europium. The influence of Eu3+ on the luminescent properties of the samples synthesized was studied by optical spectroscopy (IR, Raman, and UV visible and emission spectra).

Key words

precursor methods of synthesis infrared spectroscopy Raman spectroscopy emission spectra 
This is a preview of subscription content, log in to check access.

References

  1. 1.
    R. L. Orimi, Opt. Mater., 35, 657 (2013).CrossRefGoogle Scholar
  2. 2.
    J. Fallert, R. Hauschild, F. Stelzl, et al., J. Appl. Phys., 101, 073506 (2007).CrossRefGoogle Scholar
  3. 3.
    J. Yang, X. Li, J. Lang, et al., Mater. Sci. Semicond. Process., 14, 247 (2011).CrossRefGoogle Scholar
  4. 4.
    D. D. Wang, G. Z. Xing, J. H. Yang, et al., Alloys Comp., 504, 22 (2010).CrossRefGoogle Scholar
  5. 5.
    O. N. Gyrdasova, E. V. Shalaeva, and V. N. Krasil’nikov, “Method for obtaining nanotubes of zinc oxide (variants),” Russian Patent 2451579 C2, Publ. May 27, 2012.Google Scholar
  6. 6.
    Z. G. Wang, X. T. Zu, S. Zhu, L. M. Wan, Physics E., 35, 199 (2006).CrossRefGoogle Scholar
  7. 7.
    G. Lakshminarayana, J. Qiu, and M. G. Brik, J. Phys.: Condens. Matter, 20, 335106 (2008).CrossRefGoogle Scholar
  8. 8.
    K. Marimuthu, S. Babu, G. Muralidharan, et al., Phys. Status Solidi A, 206, 131 (2009).CrossRefGoogle Scholar
  9. 9.
    S. K. Lee, S. L. Chen, D. Hongxing, et al., Appl. Phys. Lett., 96, 083104 (2010).CrossRefGoogle Scholar
  10. 10.
    W. Y. Jia, K. Monge, and F. Fernandez, Opt. Mater., 23, 27 (2003).CrossRefGoogle Scholar
  11. 11.
    D. Wang, G. Xing, M. Gao, et al., J. Phys. Chem. C, 115, 22729 (2011).CrossRefGoogle Scholar
  12. 12.
    X. Zeng, J. Yuan and L. Zhang, J. Phys. Chem. C, 112, 3503 (2008).CrossRefGoogle Scholar
  13. 13.
    X. Y. Zeng, J. L. Yuan, Y. Z. Wang, and L. Zhang, Adv. Mater., 19, 4510 (2007).CrossRefGoogle Scholar
  14. 14.
    M. Wang, C. Juang, Z. Huang, et al., Opt. Mater., 31, 1502 (2009).CrossRefGoogle Scholar
  15. 15.
    V. X. Quang, N. Q. Liem, N. C. Thana, et al., Phys. Status Solidi A, 78, K161 (1983).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • I. V. Baklanova
    • 1
  • V. N. Krasil’nikov
    • 1
  • L. A. Perelyaeva
    • 1
  • O. I. Gyrdasova
    • 1
  1. 1.Institute of Solid State Chemistry, Ural BranchRussian Academy of SciencesEkaterinburgRussian Federation

Personalised recommendations