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Theoretical and Experimental Chemistry

, Volume 48, Issue 1, pp 14–20 | Cite as

Spectral indications of interaction of functionalized photochromic compounds with Ag and Au nanoparticles

  • V. A. BarachevskiiEmail author
  • O. I. Kobeleva
  • T. M. Valova
  • A. O. Ait
  • L. S. Kol’tsova
  • A. I. Shienok
  • N. L. Zaichenko
  • A. V. Laptev
  • A. A. Khodonov
  • O. Yu. Kuznetsova
  • A. A. Dudinov
  • B. V. Lichitskii
  • M. M. Krayushkin
Article

A comparative investigation of the photochromism of photochromic spiropyrans, spirooxazines, and diarylethenes in solutions and in solid-phase films in the absence and in the presence of silver and gold nanoparticles was undertaken by a kinetic spectral method. On the basis of the experimental data it was concluded that hybrid photochromic nanoparticles of the core–shell type can be obtained as a result of chemical reaction of functionalized molecules with the nanoparticles of noble metals.

Key words

photochromism silver and gold nanoparticles spectroscopy spiropyrans spirooxazines diarylethenes 

Notes

The work was carried out with support from the Russian Fundamental Research Fund (project No. 10-03-90023-Bel_a) and the Federal Target Program (State contract No. 16.513.11.3077).

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Copyright information

© Springer Science+Business Media, Inc. 2012

Authors and Affiliations

  • V. A. Barachevskii
    • 1
    Email author
  • O. I. Kobeleva
    • 1
  • T. M. Valova
    • 1
  • A. O. Ait
    • 1
  • L. S. Kol’tsova
    • 2
  • A. I. Shienok
    • 2
  • N. L. Zaichenko
    • 2
  • A. V. Laptev
    • 3
  • A. A. Khodonov
    • 3
  • O. Yu. Kuznetsova
    • 4
  • A. A. Dudinov
    • 4
  • B. V. Lichitskii
    • 4
  • M. M. Krayushkin
    • 4
  1. 1.Institution of Russian Academy of Sciences, Photochemistry CenterRussian Academy of SciencesMoscowRussian Federation
  2. 2.Institution of Russian Academy of Sciences, N. N. Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussian Federation
  3. 3.M. V. Lomonosov Moscow State University of Fine Chemical TechnologyMoscowRussian Federation
  4. 4.Institution of Russian Academy of Sciences, N. D. Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation

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