It is shown that conversion of nickel(II) complexes, in the composition of crystalline compounds of various structures, into nickel(III) leads to the preparation of new redox-active metal-organic skeletons. The structure of the chromophore of the metal ion and the chemical properties of the compounds formed by this process (thermal stability, reactivity) depend to an important extent on the nature of the construction blocks which makes possible the creation of new materials with controlled properties.
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 45, No. 4, pp. 239-244, July-August, 2009.
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Andriichuk, I.L., Tsymbal, L.V. & Lampeka, Y.D. Redox conversions in crystalline compounds based on macrocyclic complexes of nickel(II)/(III) and aromatic carboxylates. Theor Exp Chem 45, 252 (2009). https://doi.org/10.1007/s11237-009-9090-9
- macrocyclic complexes
- metal-organic skeletons
- coordination polymers