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Theoretical and Experimental Chemistry

, Volume 44, Issue 4, pp 245–251 | Cite as

Structure and absorption volume for hydrogen of ultramicroporous coordination polymers of copper(II) with 4,4′-bipyridine

  • E. A. Mikhalyova
  • S. V. KolotilovEmail author
  • K. S. Gavrilenko
  • P. G. Nagornyi
  • S. Golhen
  • L. Ouahab
  • V. V. Pavlishchuk
Article

Abstract

It was shown that the crystal structure, formed from a polymeric chain, consisting of copper(II) ions or binuclear complexes of copper(II) bonded with 4,4′-bipyridine, can contain pores, suitable for hydrogen molecules. An analysis of the sorption properties of such compounds with respect to hydrogen showed that these depend on the parameters of the pores.

Key words

coordination polymers adsorption of hydrogen complexes of copper(II) 4,4′-bipyridine ultramicroporous sorbents 

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Copyright information

© Springer Science+Business Media, Inc. 2008

Authors and Affiliations

  • E. A. Mikhalyova
    • 1
  • S. V. Kolotilov
    • 1
    Email author
  • K. S. Gavrilenko
    • 1
  • P. G. Nagornyi
    • 2
  • S. Golhen
    • 3
  • L. Ouahab
    • 3
  • V. V. Pavlishchuk
    • 1
  1. 1.L. V. Pizarzhevskii Institute of Physical ChemistryNational Academy of Sciences of UkraineKyivUkraine
  2. 2.Taras Shevchenko Kyiv National UniversityKyivUkraine
  3. 3.Sciences Chimiques de RennesUMR, Université de Rennes 1, CNRS 6226Rennes CedexFrance

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