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Theoretical and Experimental Chemistry

, Volume 42, Issue 5, pp 271–276 | Cite as

Sorption of hydrogen by MCM-41 molecular sieves containing nanoparticles of 3d metals or their oxides

  • S. V. Kolotilov
  • A. V. Shvets
  • N. V. Kas’yan
Article

Abstract

It was shown that the sorptive capacity for hydrogen in composites based on MCM-41 molecular sieves and nanoparticles of the oxides of 3d metals or the metals themselves at 77 K and 1 atm is determined both by the surface area and by the volume of the micropores of the samples and does not depend on the nature of the 3d metal (Ni, Co, Cu) or its degree of oxidation.

Key words

hydrogen sorption composites MCM-41 nanoparticles 3d metals 3d metal oxides correlation 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • S. V. Kolotilov
    • 1
  • A. V. Shvets
    • 1
  • N. V. Kas’yan
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical ChemistryNational Academy of Sciences of UkraineKyivUkraine

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