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Theoretical and Experimental Chemistry

, Volume 42, Issue 1, pp 43–47 | Cite as

Effect of the structure of bridging ligands on the structure and adsorption properties of 3D-coordinated copper(II) and cobalt(II) formate polymers

  • S. V. Kolotilov
  • A. V. Shvets
  • V. N. Solomakha
Article

Abstract

Increasing length of the bipyridyl bridging ligands in a series of similar complexes facilitates the formation of microporous coordination polymers. The structure of one of these compounds was found by the Rietveld method. These compounds were found to differ in their adsorption caparcities relative to methanol, nitrogen, and hydrogen.

Key words

porous coordination polymers Rietveld method methanol adsorption hydrogen adsorption 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • S. V. Kolotilov
    • 1
  • A. V. Shvets
    • 1
  • V. N. Solomakha
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical ChemistryNational Academy of Sciences of UkraineKyivUkraine

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