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Structural Chemistry

, Volume 30, Issue 6, pp 2271–2277 | Cite as

The reaction mechanism study on the decarbonylation of 2-methyl-2-propenal assisted by hydrogen chloride, water, or sulfur acid

  • Benni Du
  • Weichao ZhangEmail author
Original Research
  • 36 Downloads

Abstract

The catalytic decarbonylation reaction mechanisms of 2-methyl-2-propenal in the presence of hydrogen chloride (HCl), water (H2O), or sulfuric acid (H2SO4) have been investigated theoretically for the first time. Both concerted and stepwise mechanisms have been considered. Compared with uncatalyzed reaction, the transition state energy is decreased by 90.46, 26.35, or 146.74 kJ/mol when the reaction is carried out with HCl, H2O, or H2SO4 as a catalyst, respectively. Our calculations demonstrate that the presence of HCl can reduce the transition state energy dramatically and make the decarbonylation of 2-methyl-2-propenal to be carried out at much lower temperatures, which is consistent with the experimental result. Moreover, the lowest activation energy assisted by H2SO4 suggests that H2SO4 may have better catalytic ability than that of HCl for the decarbonylation of 2-methyl-2-propenal, and our calculational results may be useful for future experimental studies on the title reaction.

Keywords

Decarbonylation 2-methyl-2-propenal Hydrogen chloride Sulfuric acid 

Notes

Funding information

This work is jointly supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (contract grant number 10KJB150017), Doctoral Scientific Research Foundation of Jiangsu Normal University (contract grant number: 13XLR003), and A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11224_2019_1338_MOESM1_ESM.pdf (9.3 mb)
ESM 1 (PDF 9533 kb)

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.School of Chemistry and Materials ScienceJiangsu Normal UniversityXuzhouPeople’s Republic of China

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