Advertisement

Structural Chemistry

, Volume 30, Issue 1, pp 227–235 | Cite as

Benzotriazol-based structure assemble directed by transition metals

  • Ning-Ning Ji
  • Zhi-Qiang ShiEmail author
  • Hai-Liang HuEmail author
Original Research
  • 27 Downloads

Abstract

Two coordination polymers, namely [Mn(L)2(H2O)2]n (1) and [Cd2(L)4(H2O)4]n (2) {HL = (benzotriazol-1-yloxy)-acetic acid}, have been synthesized and characterized by single-crystal X-ray diffraction as well as with infrared spectroscopy and elemental analysis. The results reveal that CP1 has 1D double chain structure, while CP2 features a 1D infinite chain structure. Additionally, there both exist O–H···O and O–H···N hydrogen bonds in CP1 and CP2, forming 3D supramolecular structures, respectively. UV-vis absorption spectra of CP1, and photoluminescence property of CP2, have been examined in solid state at room temperature. The result on optical energy gap of 2.80 eV indicates that CP1 is a potential semiconductive material.

Keywords

Coordination polymers (benzotriazol-1-yloxy)-Acetic acid Photoluminescence Semiconductive material 

Notes

Funding information

This work was financially supported by the Natural Science Foundation of China (No. 21861012), the Natural Science Foundation of Shandong Province of China (No. ZR2016BM14), Tai’an Science And Technology Project (No. 2016GX1046), and the Postgraduate Foundation of Taishan University (No. Y2015-1-011).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

References

  1. 1.
    Zhang JP, Liao PQ, Zhou HL, Lin RB, Chen XM (2014). Chem Soc Rev 43:5789–5814CrossRefGoogle Scholar
  2. 2.
    Zhou HC, Kitagawa S (2014). Chem Soc Rev 43:5415–5418CrossRefGoogle Scholar
  3. 3.
    Zhou HC, Long JR, Yaghi OM (2012). Chem Rev 112:673–674CrossRefGoogle Scholar
  4. 4.
    Easun TL, Moreau F, Yan Y, Yang S, Schröder M (2017). Chem Soc Rev 46:239–274CrossRefGoogle Scholar
  5. 5.
    Agarwal RA, Gupta NK (2017). Coord Chem Rev 332:100–121CrossRefGoogle Scholar
  6. 6.
    Ni ZP, Liu JL, Hoque MN, Liu W, Li JY, Chen YC, Tong ML (2017). Coord Chem Rev 335:28–43CrossRefGoogle Scholar
  7. 7.
    Huang YB, Liang J, Wang XS, Cao R (2017). Chem Soc Rev 46:126–157CrossRefGoogle Scholar
  8. 8.
    Nath I, Chakraborty J, Verpoort F (2016). Chem Soc Rev 45:4127–4170CrossRefGoogle Scholar
  9. 9.
    Gu ZG, Zhan CH, Zhang J, Bu XH (2016). Chem Soc Rev 45:3122–3144CrossRefGoogle Scholar
  10. 10.
    Hu Z, Deibert BJ, Li J (2014). Chem Soc Rev 43:5815–5840CrossRefGoogle Scholar
  11. 11.
    Kreno LE, Leong K, Farha OK, Allendorf M, Duyne RPV, Hupp JT (2012). Chem Rev 112:1105–1125CrossRefGoogle Scholar
  12. 12.
    Lu ZZ, Zhang R, Li YZ, Guo ZJ, Zheng HG (2011). J Am Chem Soc 133:4172–4174CrossRefGoogle Scholar
  13. 13.
    Torad NL, Hu M, Kamachi Y, Takai K, Imura M, Naito M, Yamauchi Y (2013). Chem Commun 49:2521–2523CrossRefGoogle Scholar
  14. 14.
    Zhao XL, Sun WY (2014). CrystEngComm 16:3247–3258CrossRefGoogle Scholar
  15. 15.
    Huang DQ, Zhang H, Sheng LQ, Jiang XY, Liu ZD, Xu HJ (2014). Chinese J Inorg Chem 30:1641–1646Google Scholar
  16. 16.
    APEX-II, SAINT and SADABS, Bruker AXS Inc., Madison, WI, 2008Google Scholar
  17. 17.
    Sheldrick GM (2015). Acta Crystallogr Sect C 71:3–8CrossRefGoogle Scholar
  18. 18.
    Guo J, Ma JF, Li JJ, Yang J, Xing SX (2012). Cryst Growth Des 12:6074–6082CrossRefGoogle Scholar
  19. 19.
    Yin WX, Liu YT, Ding YJ, Lin Q, Lin XM, Wu CL, Yao XD, Cai YP (2015). CrystEngComm 17:3619–3626CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Chemistry and Chemical EngineeringTaishan UniversityTai’anPeople’s Republic of China
  2. 2.State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjingPeople’s Republic of China
  3. 3.School of Chemical Engineering (School of Chinese Pharmacy)Guizhou Minzu UniversityGuiyangPeople’s Republic of China

Personalised recommendations