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Structural Chemistry

, Volume 23, Issue 6, pp 2003–2017 | Cite as

Structural topology and dimensional reduction in uranyl oxysalts: eight novel phases in the methylamine–(UO2)(NO3)2–H2SeO4–H2O system

  • Vadim M. Kovrugin
  • Vladislav V. Gurzhiy
  • Sergey V. Krivovichev
Original Research

Abstract

Single crystals of eight novel uranyl selenates, (CH3NH3)2[(UO2)(SeO4)2(H2O)](H2O) (I) and (CH3NH3)2[(UO2)(SeO4)2(H2O)] (II), (CH3NH3)2[(UO2)2(SeO4)3] (III) and (CH3NH3)(H3O)[(UO2)2(SeO4)3(H2O)](H2O) (IV), (CH3NH3)4[(UO2)3(SeO4)5](H2O)4 (V) and (CH3NH3)(H5O2)(H3O)2[(UO2)3(SeO4)5](H2O)4 (VI), (CH3NH3)4(H3O)2[(UO2)5(SeO4)8(H2O)](H2O)4 (VII), and (CH3NH3)1.5(H5O2)1.5(H3O)3[(UO2)5(SeO4)8(H2O)](H2SeO4)2.6(H2O)3 (VIII), have been prepared by isothermal evaporation from aqueous solutions and structurally characterized. The observed structural topologies of uranyl selenate units have been investigated using graph theory. The principle of dimensional reduction has been used for analysis of the uranyl oxysalts with general chemical formula A n (UO2) p (TO4) q (H2O) r (A = monovalent cation, and T = S, Se, Cr, Mo), which allowed to construct three-component composition-structure diagram with separate dimensionality fields for different chemical compositions.

Keywords

Uranium Selenium Methylamine Uranyl oxysalts Crystal structure Single crystal X-ray diffraction Topology Dimensional reduction 

Notes

Acknowledgments

This study was supported by RFBR (Grant 12-03-90711 to VVG) and St. Petersburg State University through the internal grant 3.37.84.2011 and the X-Ray Diffraction Resource Center.

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Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • Vadim M. Kovrugin
    • 1
  • Vladislav V. Gurzhiy
    • 1
  • Sergey V. Krivovichev
    • 1
    • 2
  1. 1.Department of Crystallography, Faculty of GeologySt. Petersburg State UniversitySaint PetersburgRussia
  2. 2.Institute of Silicate Chemistry, Russian Academy of SciencesSaint PetersburgRussia

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