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Structural Chemistry

, Volume 23, Issue 3, pp 645–652 | Cite as

New organic–inorganic hybrid structure based on paradodecatungstate clusters and imidazolium cations

  • Sana ChaaliaEmail author
  • Jean-Claude Daran
  • Amor Haddad
Original Research

Abstract

An organic–inorganic hybrid material based on paradodecatungstate anions and imidazolium cations, Na2(HIm)8(H2W12O42)·10H2O (HIm: imidazolium), has been synthesized under mildly acidic conditions. This compound was characterized by single-crystal X-ray diffraction, IR and UV–visible spectroscopies, and thermogravimetric and differential thermal analyses. The compound crystallizes in the triclinic P-1 space group with a = 11.6945(8) Å, b = 12.4782(6) Å, c = 14.0952(9) Å, α = 106.041(3)°, β = 109.338(2)°, γ = 100.249(3)°, V = 1781.0(3) Å3, and Z = 2. The crystal structure exhibits an infinite 1D inorganic structure built from [H2W12O42]10− clusters and sodium cations; adjacent chains are further joined up by hydrogen-bonding interactions between protonated imidazole cations, water molecules, and polyoxoanions, to form a 3D supramolecular architecture.

Keywords

Organic–inorganic hybrid Polyoxometalate Paradodecatungstate Imidazole 

Notes

Acknowledgments

This study was supported by the Ministry of Higher Education and Scientific Research of Tunisia.

References

  1. 1.
    Pope MT (1983) Heteropoly and isopolyoxometalates. Springer, New YorkGoogle Scholar
  2. 2.
    Pope MT, Müller A (1994) Polyoxometalates: from platonic solids to anti-retroviral activity. Kluwer Academic Publishers, DordrechtCrossRefGoogle Scholar
  3. 3.
    Müller A, Peters F, Pope MT, Gatteschi D (1998) Chem Rev 98:239CrossRefGoogle Scholar
  4. 4.
    Kozhenikov IV (1998) Chem Rev 98:171CrossRefGoogle Scholar
  5. 5.
    Proust A, Thouvenot R, Gouzerh P (2008) Chem Commun 16:1837CrossRefGoogle Scholar
  6. 6.
    Keita B, Nadjo L (2006) In: Bard AJ, Stratmann M (eds) Encyclopedia of electrochemistry, vol 7. Wiley, New YorkGoogle Scholar
  7. 7.
    Rhule JT, Hill CL, Judd DA, Schinazi RF (1998) Chem Rev 98:327CrossRefGoogle Scholar
  8. 8.
    He T, Yao J (2006) Prog Mater Sci 51:810CrossRefGoogle Scholar
  9. 9.
    Clemente-Juan JM, Coronado E (1999) Coord Chem Rev 361:193Google Scholar
  10. 10.
    Müller A, Shah SQN, Bogge H, Schmidtmann M (1999) Nature 397:48CrossRefGoogle Scholar
  11. 11.
    Katsoulis DE (1998) Chem Rev 98:359CrossRefGoogle Scholar
  12. 12.
    Razak IA, Raj SSS, Chantrapromma S, Fun HK, Zhou YS, You XZ (2001) J Chem Crystallogr 31:255CrossRefGoogle Scholar
  13. 13.
    Legagneux N, Jeanneau E, Basset JM, Lefebvre F (2009) J Mol Struct 921:300CrossRefGoogle Scholar
  14. 14.
    Ma H, Gong L, Wang F, Wang X (2008) Struct Chem 19:435CrossRefGoogle Scholar
  15. 15.
    Gouzerh P, Proust A (1998) Chem Rev 98:77CrossRefGoogle Scholar
  16. 16.
    Dablemont C, Hamaker CG, Thouvenot R, Sojka Z, Che M, Maatta EA, Proust A (2006) Chem Eur J 12:9150CrossRefGoogle Scholar
  17. 17.
    Dolbecq A, Dumas E, Mayer CR, Mialane P (2010) Chem Rev 110:6009CrossRefGoogle Scholar
  18. 18.
    Dufaud V, Lefebvre F (2010) Materials 3:682CrossRefGoogle Scholar
  19. 19.
    Galan-Mascaros JR, Gimenez-Saiz C, Triki S, Gomez-Garcia CJ, Coronado E, Ouahab L (1995) Angew Chem Int Ed 34:1460CrossRefGoogle Scholar
  20. 20.
    Inouye Y, Fujimoto Y, Sugiyama M, Yoshida T, Yamase T (1995) Biol Pharm Bull 18(7):996CrossRefGoogle Scholar
  21. 21.
    Hill CL, Hartnup M, Faraj M, Weeks M, Prosser-McCartha CM, Brown RB Jr, Kadkhodayan M, Sommadossi JP, Schinazi RF (1990) In: Diasio RB, Sommadossi JP (eds) Advances in Chemotherapy of AIDS. Pergamon Press Inc., New YorkGoogle Scholar
  22. 22.
    Lin BZ, Chen YM, Liu PD (2003) Dalton Trans 12:2474CrossRefGoogle Scholar
  23. 23.
    He LW, Lin BZ, Liu XZ, Huang XF, Feng YL (2008) Solid State Sci 10(3):237CrossRefGoogle Scholar
  24. 24.
    Gainsford GJ, Robinson N, Tallon JL (2002) Acta Cryst E 58:521CrossRefGoogle Scholar
  25. 25.
    Loose I, Bosing M, Klein R, Krebs B, Schulz RP, Scharbert B (1997) Inorg Chim Acta 263:99CrossRefGoogle Scholar
  26. 26.
    Lisnard L, Dolbecq A, Mialane P, Marrot J, Secheresse F (2004) Inorg Chim Acta 357:845CrossRefGoogle Scholar
  27. 27.
    Feng YQ, Huang QZ, Qiu DF, Meng ZH (2010) Russ J Coord Chem 36(7):541CrossRefGoogle Scholar
  28. 28.
    Chen Y, Peng J, Pang HJ, Tian AX, Zhang PP, Chen D, Zhu M, Wang Y, Ma H (2009) Inorg Chem Commun 12:1242CrossRefGoogle Scholar
  29. 29.
    Chaalia S, Ayed B, Haddad A (2011) Struct Chem 22(1):167CrossRefGoogle Scholar
  30. 30.
    Dutta D, Maity D, Ali M, Drew MGB, Mondal S, Mukherjee M (2008) Transition Met Chem 33:347CrossRefGoogle Scholar
  31. 31.
    Bhandari K, Srinivas N, Marrapu VK, Verma A, Srivastava S, Gupta S (2010) Bioorg Med Chem Lett 20:291CrossRefGoogle Scholar
  32. 32.
    Gong Y, Hu CW, Li H, Huang KL, Tang W (2005) J Solid State Chem 178:3152CrossRefGoogle Scholar
  33. 33.
    Xiaoqiang C, Sunwoo K, Kim MJ, Kim J, Kim YS, Kim H, Chi B, Kim SJ, Lee JY, Yoon J (2010) Angew Chem Int Ed 49:1422CrossRefGoogle Scholar
  34. 34.
    An H, Zheng H, Xu T, He C, Wang J, Wu P, Duan C (2010) Z Anorg Allg Chem 636:2016CrossRefGoogle Scholar
  35. 35.
    Liu H, Peng J, Su Z, Chen Y, Dong B, Tian A, Han Z, Wang E (2006) Eur J Inorg Chem 2006(23):4827CrossRefGoogle Scholar
  36. 36.
    He X, Ye JW, Xu JN, Fan Y, Wang L, Zhang P, Wang Y (2005) J Mol Struct 749:9CrossRefGoogle Scholar
  37. 37.
    Tian CH, Sun ZG, Li J, Zheng XF, Liang HD, Zhang LC, You WS, Zhu ZM (2007) Inorg Chem Commun 10:757CrossRefGoogle Scholar
  38. 38.
    Chen Y, Zhang H, Huang C, Cao Y, Sun R, Guo W (2006) Spectrochim Acta A 63:536CrossRefGoogle Scholar
  39. 39.
    Zhao L, Luo X, Xu L, Jiang N, Li F, Li Y (2010) Inorg Chem Commun 13:554CrossRefGoogle Scholar
  40. 40.
    Li L, Liu B, Xue G, Hu H, Fu F, Wang (2009) J Cryst Growth Des 9(12):5206CrossRefGoogle Scholar
  41. 41.
    Jin H, Zhou B, Wang C, Su Z, Zhao Z, Zhang Y, Zhu C (2009) Inorg Chem Commun 12:76CrossRefGoogle Scholar
  42. 42.
    Liu XM, Wang CR, Liu B, Xue GL, Hu HM, Wang JW, Fu F (2005) Chin J Chem 23:1412CrossRefGoogle Scholar
  43. 43.
    Liu H, Liu Y, Liu H, Shi C, Liu F, Liu H (2009) Inorg Chem Commun 12:1CrossRefGoogle Scholar
  44. 44.
    Sheldrick GM (1997) SHELXL 97, program for crystal structure refinement. University of Gottingen, GermanyGoogle Scholar
  45. 45.
    Lin BZ, Chen YM, Liu PD (2003) J Chem Soc Dalton Trans 12:2474Google Scholar
  46. 46.
    Allmann VR (1971) Acta Crystallogr B 27:1393CrossRefGoogle Scholar
  47. 47.
    Evans HT Jr, Prince E (1983) J Am Chem Soc 105:4838CrossRefGoogle Scholar
  48. 48.
    Gimenez-Saiz C, Galan-Mascaros JR, Triki S, Coronado E, Ouahab L (1995) Inorg Chem 34:524CrossRefGoogle Scholar
  49. 49.
    Brown ID, Altermatt D (1985) Acta Crystallogr B 41:244CrossRefGoogle Scholar
  50. 50.
    Lipscomb WN (1965) Inorg Chem 4:132CrossRefGoogle Scholar
  51. 51.
    Xu H, Wang XL, Li YG, Wang EB, Qin C, Si YL (2007) Inorg Chem Commun 10(3):276CrossRefGoogle Scholar
  52. 52.
    George BL, Aruldhas G, Botto IL (1992) J Mater Sci Lett 11:1421CrossRefGoogle Scholar
  53. 53.
    Flakus HT, Bryk A (1996) J Mol Struct 385:35CrossRefGoogle Scholar
  54. 54.
    Kurzepa M, Dobrowolski JC, Mazurek AP (2001) J Mol Struct 565–566:107CrossRefGoogle Scholar
  55. 55.
    Zhao J, Song Y, Ma P, Wang J, Niu J (2009) J Solid State Chem 182:1798CrossRefGoogle Scholar
  56. 56.
    Wang JP, Ren Q, Zhao JW, Niu JY (2006) Chin J Struct Chem 25(10):1167Google Scholar
  57. 57.
    Serrano-Andres L, Fulscher MP, Roos BO, Merchan M (1996) J Phys Chem 100:6484CrossRefGoogle Scholar
  58. 58.
    Weiner H, Lunk HJ, Friese R, Hartl H (2005) Inorg Chem 44:7751CrossRefGoogle Scholar
  59. 59.
    Kirilenko O, Girgsdies F, Jentoft RE, Ressler T (2005) Eur J Inorg Chem 11:2124CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  1. 1.Laboratoire des Matériaux et Cristallochimie (LMC)Institut Supérieur des Sciences Appliquées et TechnologieMahdiaTunisia
  2. 2.Laboratoire de Chimie de Coordination (LCC)CNRS-Université de ToulouseToulouseFrance

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